5997-56-8

Basic information

• Product Name: 4-methyl-N-(oxiran-2-ylmethyl)benzenesulfonamide
• Synonyms: 4-methyl-N-(oxiran-2-ylmethyl)benzenesulfonamide
• CAS NO: 5997-56-8
• Molecular Weight: 227.284
• Mol File: 5997-56-8.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 4-methyl-N-(oxiran-2-ylmethyl)benzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methyl-N-(oxiran-2-ylmethyl)benzenesulfonamide(5997-56-8)
• EPA Substance Registry System: 4-methyl-N-(oxiran-2-ylmethyl)benzenesulfonamide(5997-56-8)

Safety Data

• Hazardous Substances Data: 5997-56-8(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 70-55-3 toluene-4-sulfonamide 
• 50487-71-3 4-methyl-N-(2-propenyl)benzenesulfonamide 

Downstream Products

• 779358-19-9 (2-methyl-1-{[oxiranylmethyl-(toluene-4-sulfonyl)-amino]-methyl}-propenyl)-phosphonic acid diethyl ester 
• 779357-82-3 N-[2-(diphenyl-phosphinoyl)-3-methyl-but-2-enyl]-4-methyl-N-oxiranylmethyl-benzenesulfonamide 
• 779357-84-5 N-[2-(diphenyl-phosphinoyl)-4-methyl-pent-2-enyl]-4-methyl-N-oxiranylmethyl-benzenesulfonamide 
• 779357-96-9 N-[3-cyclopropyl-2-(diphenyl-phosphinoyl)-allyl]-4-methyl-N-oxiranylmethyl-benzenesulfonamide 
• 779357-88-9 N-[2-cyclobutylidene-2-(diphenyl-phosphinoyl)-ethyl]-4-methyl-N-oxiranylmethyl-benzenesulfonamide 
• 779357-86-7 N-[2-(diphenyl-phosphinoyl)-3-phenyl-allyl]-4-methyl-N-oxiranylmethyl-benzenesulfonamide 
• 779357-92-5 N-[2-cyclohexylidene-2-(diphenyl-phosphinoyl)-ethyl]-4-methyl-N-oxiranylmethyl-benzenesulfonamide 
• 779357-94-7 N-[2-(1,4-dioxa-spiro[4.5]dec-8-ylidene)-2-(diphenyl-phosphinoyl)-ethyl]-4-methyl-N-oxiranylmethyl-benzenesulfonamide 
• 801294-04-2 4-methyl-N-oxiranylmethyl-N-Prop-2-ynyl-benzenesulfonamide 
• 210972-39-7 N-(p-toluenosulfonyl)-2-hydroxymethylaziridine 

Relevant articles and documents

Regio- and chemoselective rearrangement of terminal epoxides into methyl alkyl and aryl ketones

The development of the highly active pincer-type rhodium catalyst 2 for the nucleophilic Meinwald rearrangement of functionalised terminal epoxides into methyl ketones under mild conditions is presented. An excellent regio- and chemoselectivity is obtained for the first time for aryl oxiranes.

NIS-mediated ring-closure/opening cascade reactions of allylamides: An expedient route to oxazolines

An unprecedented NIS-mediated ring-closure/opening cascade reaction of allylamides is developed. The substrates with various functionalities were well tolerated and the scope can be extended to allylic carboxylates. Notably, the resulting iodinated chain

Copper-catalyzed trifluoromethylation and cyclization of aromatic-sulfonyl-group-tethered alkenes for the construction of 1,2-benzothiazinane dioxide type compounds

A multi-talented system: An efficient copper-catalyzed tandem trifluoromethylation/annulation of an electron-deficient aromatic ring has been developed. This method provides a powerful and straightforward way to synthesize trifluoromethylated 1,2-benzothiazinane dioxides under mild conditions (see scheme). The mechanism was investigated by a series of kinetic experiments and isotopic labeling studies.