77958-30-6Relevant academic research and scientific papers
Reactions of 2-(2-propenyl)-3-chloromethyloxirane with benzene
Akhmedov, M.A.,Sardarov, I.K.,Akhmedov, I.M.,Kostikov, R.R.,Babaev, N.M.,Shukyurova, M.B.
, p. 2025 - 2028 (2007/10/02)
The reaction of 2-(2-propenyl)-3-chloromethyloxirane with benzene in the presence of aluminum chloride gives a 3:6:1 mixture of 1,4-dichloro-2-hexanone, 1-chloro-4-phenyl-2-hexanone, and 1-chloro-3,4-diphenyl-2-hexanone
Acylation du (cyclopropylmethyl)trimethylsilane. Une nouvelle voie d'acces aux enones non conjuguees
Grignon-Dubois, M.,Dunogues, J.,Calas, R.
, p. 802 - 806 (2007/10/02)
Acylation of (cyclopropylmethyl)trimethylsilane using RCOCl/AlCl3 (R: saturated hydrocarbon group) constitutes a mild, convenient route to β,γ-unsaturated ketones free from the conjugated isomers.With α,β-unsaturated acyl chlorides a competitive reaction between the C-H and C-Si allylic cleavage is observed whereas chloroacetyl chloride affords the γ,δ-ethylenic corresponding ketone.A mechanism involving the catalytic role of HCl in the formation of β,γ-unsaturated and chloroketones is proposed.
