77971-03-0Relevant academic research and scientific papers
Palladium-Catalyzed Cross-Coupling of Aryl Halides and Olefinic Epoxides via Palladium Migration
Larock, Richard C.,Leung, Wai-Yee
, p. 6244 - 6245 (2007/10/02)
The palladium-catalyzed cross-coupling of aryl halides and olefinic epoxides bearing one to ten carbons between the two functional groups afford good yields of arylated allylic alcohols by a palladium migration process.
A STEREOSELECTIVE SYNTHESIS OF β,γ-DISUBSTITUTED ALLYLIC ALCOHOLS OF Z-CONFIGURATION
Tamura, Mitsuhisa,Suzukamo, Gohu
, p. 577 - 580 (2007/10/02)
Reaction of alkyllithiums 1 with isoprene epoxide 2 gives β,γ-disubstituted allylic alcohols 3 of Z-configuration.The reaction of ?-lithiotricyclene as alkyllithium gives α-santalol 5, which is one of the main constituents in East Indian sandalwood oil.
