42808-98-0

Basic information

• Product Name: Lithium, (2-phenylethyl)-
• CAS NO: 42808-98-0
• Molecular Formula: C8H9Li
• Molecular Weight: 112.1
• Mol File: 42808-98-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Lithium, (2-phenylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Lithium, (2-phenylethyl)-(42808-98-0)
• EPA Substance Registry System: Lithium, (2-phenylethyl)-(42808-98-0)

Safety Data

• Hazardous Substances Data: 42808-98-0(Hazardous Substances Data)

Upstream product

• 13865-49-1 [2-(phenylsulfanyl)ethyl]benzene 
• 956-73-0 bis-β-phenylethylmercury 
• 17376-04-4 2-phenethyl iodide 
• 103-63-9 1-phenyl-2-bromoethane 

Downstream Products

• 122445-15-2 (3,4,4-Trimethyl-pentyl)-benzene 
• 100-41-4 ethylbenzene 
• 17988-51-1 1-Ethyl-3-trimethylsilylbenzol 
• 17988-50-0 (4-ethylphenyl)trimethylsilane 
• 81632-00-0 C₁₀H₁₀⁽²⁾H₄ 
• 81631-56-3 C₁₅H₁₈⁽²⁾H₈OSi 
• 81631-55-2 C₁₂H₁₀⁽²⁾H₈O 
• 772-64-5 (phenylethyl)silane 
• 777-82-2 1-phenyl-4-trimethylsilyl-butane 
• 18411-98-8 Trimethyl-<3-(2-trimethylsilyl-aethyl)-phenyl>-silan 
• 2762-93-8 (1-phenylethane-1,2-diyl)bis(trimethylsilane) 
• 81631-54-1 C₁₆H₃₀Si₂ 
• 122445-14-1 (3-cyclohexylbutyl)benzene 
• 54410-69-4 1-Phenyl-3-methylpentane 

Relevant articles and documents

Reductive lithiation of alkyl phenyl sulfides in diethyl ether. A ready access to α,α-dialkylbenzyllithiums

Diethyl ether is a convenient solvent for the conversion of benzylic phenyl sulfides to the corresponding organolithiums by an uncatalyzed reductive metalation, while catalysis by naphthalene is required to achieve the same reaction for alkyl phenyl sulfides. The addition of magnesium 2-ethoxyethoxide to solutions of unstable alkyllithiums prepared in this way provides storable reagents.

Clean and Convenient Procedure for Converting Primary Alkyl Iodides and α,ω-Diiodoalkanes into the Corresponding Alkyllithium Derivatives by Treatment with tert-Butyllithium

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