78019-45-1Relevant academic research and scientific papers
Enantioselective synthesis of benzylic stereocentres via Claisen rearrangement of enantiomerically pure allylic alcohols: Preparation of (R)- and (S)-3-methyl-2-phenylbutylamine
Brenna, Elisabetta,Fuganti, Claudio,Gatti, Francesco G.,Passoni, Massimo,Serra, Stefano
, p. 2401 - 2406 (2007/10/03)
The Johnson-Claisen rearrangement of enantiopure allylic alcohols in triethylorthopropionate is the key step for the preparation of chiral molecules with benzylic stereogenic carbon atoms bearing an isopropyl moiety. The synthetic procedure is applied to the preparation of (R)- and (S)-3-methyl-2-phenylbutylamine.
Metal Catalysis in Organic Reactions. 12. Asymmetric Induction Phenomena in the Isomerization of Racemic 1-Alkenes by Chiral Aluminum Solvate-Nickel Systems
Giacomelli, Giampaolo,Bertero, Luigi,Lardicci, Luciano,Menicagli, Rita
, p. 3707 - 3711 (2007/10/02)
The isomerization of some racemic 1-alkenes in the presence of chiral amine-triisobutylaluminum solvate-bis(N-methylsalicylaldimine)nickel systems has been studied.The susceptibility to isomerization of the alkenes was found to be related to their structu
