78024-75-6Relevant academic research and scientific papers
COPPER(I)-PROMOTED COUPLING REACTION OF ARYL HALIDES WITH SODIUM DIETHYLMALONATE
Setsune, Jun-ichiro,Matsukawa, Kimihiro,Wakemoto, Hirofumi,Kitao, Teijiro
, p. 367 - 370 (1981)
Copper(I)-promoted coupling reaction of aryl halides with sodium diethylmalonate occured smoothly in dioxane.The qualitative trends in the activity of copper(I) salt followed the order: CuBr > CuI > CuBF4(CH3CN)4 > CuCl.The activity was lowered in the presence of coordinating molecule such as acetonitrile, pyridine, NaI, phosphine, and sulfide.The reaction was generally applicable to aryl halides with various substituents.
