78073-67-3Relevant academic research and scientific papers
BORONIC ACID DERIVATIVES AND THERAPEUTIC USES THEREOF
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Paragraph 0277, (2016/02/28)
Disclosed herein are antimicrobial compounds compositions, pharmaceutical compositions, the use and preparation thereof. Some embodiments relate to boronic acid derivatives and their use as therapeutic agents.
New Insights on the Reaction of Alkyl 3-Oxo-4-(triphenylphosphoranylidene)butanoate and Aldehydes under Concentrated Condensation Conditions. One-Pot Synthesis of Highly functionalised 6-Oxocyclohex-4-ene-1,3-dicarboxylates
Moorhoff, Cornelis M.,Schneider, David F.,Winkler, Dave
, p. 3461 - 3483 (2007/10/03)
New annulation methodologies for the construction of substituted cyclohex-2-enones are important in organic synthesis. In this paper wee describe a new one-pot synthesis of substituted cyclohexenonedicarboxylates in maximum yield of 52 percent from the condensation of alkyl 3-oxo-4-(triphenylphosphoranylidene)-butanoate 1 and aldehydes.
Synthesis of Saturated Anacardic Acids, and Alkenyl and Alkynyl Analogues
Tyman, John H. P.,Visani, Naina
, p. 228 - 240 (2007/10/03)
The C-alkylation of esters of 2-methoxy-6-methylbenzoic acid and of the 4-methyl isomers affords a route to homologous compounds including in the former case members of the natural anacardic acids from Anacardium occidentale and ω-alkynyl compounds suitable for synthesising other natural phenolic lipids or for structure/activity studies.
Reactions of 1-aza-1,3-butadienes. A novel synthesis of 6-acetyl- and 6-methoxycarbonyl-5-methyl-2-cyclohexenones
Geirsson,Gudmundsdottir
, p. 993 - 994 (2007/10/02)
The readily available N-tert-butyl-1-aza-1,3-pentadiene [N-(2-butenylidene)-2-methyl-2-propylamine] reacts with acetylacetone and methyl acetoacetate under acid-catalyzed reaction conditions to afford 6-acetyl- and 6-methoxycarbonyl-5-methyl-2-cyclohexenones, respectively, in good yield.
CONDENSATION OF ETHYL AND METHYL 4-(TRIPHENYLPHOSPHORANYLIDENE)-3-OXOBUTANOATE WITH ENALS
Moorhoff, Cornelis M.,Schneider, David F.
, p. 4721 - 4724 (2007/10/02)
The manipulation of the mode of reaction of 4-(phosphoranylidene)-3-oxobutanoates with enals and a resulting new synthesis of ethyl β-safranate have been explored.
COMMENTS ON THE REACTION OF ETHYL 4-(DIETHOXYPHOSPHINYL)-3-OXOBUTANOATE AND RELATED PHOSPHONATE ESTERS WITH ENALS
Moorhoff, Cornelis M.,Schneider, David F.
, p. 559 - 562 (2007/10/02)
The reaction pathways followed by the mono- and dianions of 4-phosphinyl-3-oxobutanoates during their condensation with α,β-unsaturated carbonyl compounds are discussed.
