78087-00-0Relevant academic research and scientific papers
Identification of a valuable kinetic process in copper-catalyzed asymmetric allylic alkylation
Langlois, Jean-Baptiste,Alexakis, Alexandre
, p. 1877 - 1881 (2011/04/16)
Copper bottomed: The application of a previously described process of dynamic kinetic asymmetric transformation to acyclic substrates allowed the identification of a relevant kinetic process in the title reaction (see scheme; CuTC= copper(I) thiophencarboxylate, Naphth= naphthyl). The optimization of the reaction conditions and generality of the method, as well as mechanistic considerations are disclosed.
Metal Catalysis in Organic Reactions. 12. Asymmetric Induction Phenomena in the Isomerization of Racemic 1-Alkenes by Chiral Aluminum Solvate-Nickel Systems
Giacomelli, Giampaolo,Bertero, Luigi,Lardicci, Luciano,Menicagli, Rita
, p. 3707 - 3711 (2007/10/02)
The isomerization of some racemic 1-alkenes in the presence of chiral amine-triisobutylaluminum solvate-bis(N-methylsalicylaldimine)nickel systems has been studied.The susceptibility to isomerization of the alkenes was found to be related to their structu
