78094-77-6

Upstream product

• 78094-68-5 (4R^*,5R^*)-4,5-dimethyl-2-tetrahydropyranol 
• 78094-72-1 (5R,6R,2E)-7-tetrahydropyranyloxy-2,5,6-trimethyl-2-heptenol 
• 78094-71-0 ethyl(5R,6R,2E)-7-tetrahydropyranyloxy-2,5,6-trimethyl-2-heptenoate 
• 78094-74-3 (2R,3R,5E,9Z)-2,3,6,10-tetramethyl-8-phenylsulfonyl-5,9-dodecadien-1-ol THP ether 
• 78148-72-8 (3R,4R)-(+)-3,4-dimethyl-5-pentanolide 
• 78148-69-3 (3R^*,4R^*)-(+/-)-3,4-dimethyl-5-pentanolide 
• 78094-69-6 (5R,6R,2E)-7-hydroxy-2,5,6-trimethyl-2-heptenoate 
• 78094-76-5 (2R^*,3R^*,5E,9Z)-2,3,6,10-tetramethyl-5,9-dodecadien-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 
• 78094-74-3 (2R^*,3R^*,5E,9Z)-2,3,6,10-tetramethyl-8-phenylsulfonyl-5,9-dodecadien-1-ol THP ether 
• 78094-71-0 ethyl(5R^*,6R^*,2E)-7-tetrahydropyranyloxy-2,5,6-trimethyl-2-heptenoate 
• 78094-75-4 (2R^*,3R^*,5E,9Z)-2,3,6,10-tetramethyl-5,9-dodecadien-1-ol THP ether 
• 78094-73-2 (5R^*,6R^*,2E)-7-tetrahydropyranyloxy-2,5,6-trimethyl-2-heptenyl bromide 
• 78094-72-1 (5R^*,6R^*,2E)-7-tetrahydropyranyloxy-2,5,6-trimethyl-2-heptenol 

Relevant academic research and scientific papers

Regio- and Stereoselective Allylic Substitutions of Chiral Secondary Alkylcopper Reagents: Total Synthesis of (+)-Lasiol, (+)-13-Norfaranal, and (+)-Faranal

Chiral secondary alkylcopper reagents were prepared from chiral secondary alkyl iodides by a retentive I/Li exchange followed by a retentive transmetalation with CuBr?P(OEt)3. Switching the solvent to THF significantly increased their configura

Synthesis of (3S*,4R*,6E,10Z)-3,4,7,11-tetramethyltrideca6,10-dienal (faranal) using stereospecific 1,4-cis-hydrogenation of conjugated double bonds

(±)-Faranal was synthesised by a convergent route involving 1,4-cis-hydrogenation of two properly substituted conjugated diene building blocks to introduce stereospecifically the 6(E) and 10(Z) double bonds of the final target molecule. meso-2,3-Dimethyls

SYNTHESIS OF OPTICALLY ACTIVE FORMS OF FARANAL, THE TRAIL PHEROMONE OF PHARAOH'S ANT

(3S, 4R)-(+)-Faranal and its antipode were synthesized.The former was comparable in bioactivity with that of the natural pheromone.