78099-96-4

Upstream product

• 37523-64-1 fac-[bromo(1,2-bis(diphenylphosphino)ethane)tricarbonylmanganese(I)] 
• 7601-90-3 perchloric acid 

Downstream Products

• 112079-35-3 (Mn(CO)3((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(PH(C₆H₅)2))⁽¹⁺⁾*ClO₄^(1-)=(Mn(CO)3((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(PH(C₆H₅)2))ClO₄ 
• 1192406-60-2 fac-[Mn(N-phenylimidazole)(CO)3(Ph₂PCH₂CH₂PPh₂)]ClO₄ 
• 78129-40-5 fac-[Mn(CO)3(dpe)(Py)]ClO₄ 
• 57298-06-3 fac-[Mn(NCMe)(CO)3(1,2-bis(diphenylphosphino)ethane)][ClO₄] 
• 78251-35-1 fac-[Mn(CO)3(dpe)(P(OPh)3)]ClO₄ 
• 78100-00-2 fac-[Mn(CO)3(dpe)(P(OMe)3)]ClO₄ 
• 78129-42-7 fac-[Mn(CO)3(dpe)(THT)]ClO₄ 
• 93442-19-4 Mn(CO)3((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(CCC₆H₅) 
• 93442-20-7 Mn(CO)3((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(CCH) 

Relevant academic research and scientific papers

NHC-manganese(i) complexes as carbene transfer agents

Tautomerization of coordinated azoles to their corresponding N-heterocyclic carbenes (NHCs) has been carried out by reaction of complexes fac-[Mn(L)(CO)3(dppe)]+ (L = N-phenylimidazole) and fac-[Mn(L)(CO)3(bipy)]+/su

CATIONIC CARBONYL COMPLEXES OF MANGANESE(I) WITH DIPHOSPHINES

The bromo-carbonyls fac-BrMn(CO)3(diphos)(diphos=Ph2P(CH2)nPPh2 for n=1(dpm), 2(dpe), 3(dpp) and 4(dbp)) react with AgClO4 in dichloromethane solution to give the neutral fac-O3ClOMn(CO)3(diphos).The reaction of the latter complexes at room temperature with a variety of ligands L=phosphines (PR3), phosphites P(OR)3), pyridine (Py), acetonitrile (MeCN), tetrahydrothiophene (THT) or acetone (Me2CO) leads to the cationic species fac-ClO4 (or to the ClO4, when L=CO).When L is a phosphorus ligand, the cationic fac-tricarbonyls isomerize upon heating to the mer isomers, which could only be isolated by this method for diphos=dpm, the reaction being accompanied by decomposition in the other cases.UV irradiation of the mer-ClO4 in the presence of a large excess of L gives the corresponding trans-ClO4.