78132-76-0Relevant academic research and scientific papers
Total synthesis of (+)-crocacin D
Dias, Luiz C.,De Oliveira, Luciana G.,Vilcachagua, Janaina D.,Nigsch, Florian
, p. 2225 - 2234 (2007/10/03)
(Chemical Equation Presented) The total synthesis of (+)-crocacin D is described. The convergent asymmetric synthesis relies on the use of a Stille cross-coupling between an (E)-vinyl stannane with an (E)-vinyl iodide to establish the (E,E)-dienamide moie
TRIPHENYLCARBENIUM AND TRIS(P-BROMOPHENYL)AMMONIUMYL ION INDUCED LACTONIZATIONS OF ω-BENZYLOXY AND ω-P-METHOXYBENZYLOXY METHYL ESTERS
Hoye, Thomas R.,Kurth, Mark J.,Lo, Vincent
, p. 815 - 818 (2007/10/02)
The title reaction leads to smooth generation of five and six membered lactones via direct nucleophilic participation of the carbomethoxy group in intermediates of type 3.
