78133-04-7Relevant academic research and scientific papers
Effect of Basicity on the Decomposition of the Conjugate Base of 4-Nitrophenyl N-aryl-P-phenylphosphonamidates
Bourne, Nicholas,Williams, Andrew
, p. 265 - 268 (2007/10/02)
The hydrolyses at 25 deg C in 50percent ethanol-water and 1M ionic strength of the title compounds in alkaline solutions obey the equation kobs = k0/(1 + Kw/Ka->) where k0 is the rate co
PHOTOLYTIC REARRANGEMENT OF PHOSPHORUS AZIDE : EVIDENCE FOR A TRANSIENT METAPHOSPHONIMIDATE.
Bertrand, Guy,Majoral, Jean-Pierre,Baceiredo, Antoine
, p. 5015 - 5018 (2007/10/02)
Photolysis of the oxide of diphenylphosphine azide gives rise to a transient metaphisphonimidate, a new tricoordinated pentavalent phosphorus compound.Evidence for this species was given by trapping reactions on a variety of substrates.
