78135-03-2Relevant academic research and scientific papers
Mild two-step process for the transition-metal-free synthesis of carbon-carbon bonds from allylic alcohols/ethers and grignard reagents
Han, Xinping,Zhang, Yanhua,Wu, Jimmy
supporting information; experimental part, p. 4104 - 4106 (2010/05/15)
Chemical Equation Represented A mild two-step process for the regioselective, transition-metal-free preparation of carbon-carbon bonds from allylic alcohols/ethers and Grignard reagents is described. This process obviates the need for the harsh deprotecti
Mechanism of the Ni(0)-catalyzed vinylcyclopropane-cyclopentene rearrangement
Wang, Selina C.,Troast, Dawn M.,Conda-Sheridan, Martin,Zuo, Gang,LaGarde, Donna,Louie, Janis,Tantillo, Dean J.
supporting information; experimental part, p. 7822 - 7833 (2010/01/16)
(Chemical Equation Presented) A combination of physical organic experiments and quantum chemical calculations were used to construct a detailed mechanistic model for the Ni(0)-N-heterocyclic carbene-catalyzed vinylcyclopropane- cyclopentene rearrangement
REACTION OF DIAZONIUM SALTS WITH TRANSITION METALS-III. PALLADIUM(0)-CATALYZED ARYLATION OF UNSATURATED COMPOUNDS WITH ARENEDIAZONIUM SALTS
Kikukawa, K.,Nagira, K.,Wada, F.,Matsuda, T.
, p. 31 - 36 (2007/10/02)
Palladium (0) catalyzed reactions of arenediazonium salts for arylation of aliphatic and cyclic olefins and allylic alcohols, styrene and ethyl acrylate were studied.Effect of the olefinic compounds and other reaction variables on the arylation were presented.Arylpalladium species was proposed as the most plausible intermediated in this reaction.
