78140-97-3Relevant articles and documents
Synthesis of Acyl Azides from 1,3-Diketones via Oxidative Cleavage of Two C-C Bonds
Yu, Tian-Yang,Zheng, Zhao-Jing,Dang, Tong-Tong,Zhang, Fang-Xia,Wei, Hao
, p. 10589 - 10594 (2018/09/06)
A metal-free PhI(OAc)2-mediated method for the synthesis of acyl azides through oxidative cleavage of 1,3-diketones is described. This method is shown to have a broad substrate scope, providing a useful tool for multiproduct synthesis in a single procedure. A possible reaction pathway is proposed based on mechanistic studies.