78148-01-3

Upstream product

• 98-88-4 benzoyl chloride 
• 6752-48-3 methyl 2-deoxy-4,6-O-benzylidene-α-D-ribo-hexopyranoside 
• 6752-48-3 methyl 4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 33535-04-5 methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside 

Downstream Products

• 65011-66-7 methyl 3-O-benzoyl-2-deoxy-α-D-ribo-hexopyranoside 
• 65011-72-5 methyl 6-O-(tert-butyldiphenylsilyl)-4-C-(carboxymethyl)-2,4-dideoxy-α-D-ribo-hexopyranoside, γ-lactone 
• 65011-68-9 methyl 3-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-2-deoxy-α-D-erythro-hexopyranosid-4-ulose 
• 65011-67-8 methyl 3-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-2-deoxy-α-D-ribo-hexopyranoside 
• 65011-77-0 Benzoic acid (2S,3S,4S,6S)-2-formyl-6-methoxy-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-4-yl ester 
• 65011-76-9 Benzoic acid (2S,3S,4S,6S)-2-hydroxymethyl-6-methoxy-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-4-yl ester 
• 65011-78-1 Benzoic acid (2R,3S,4S,6S)-6-methoxy-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-2-((E)-3-oxo-oct-1-enyl)-tetrahydro-pyran-4-yl ester 
• 65011-74-7 (Z)-7-[(2S,3S,4S,6S)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-4-hydroxy-6-methoxy-tetrahydro-pyran-3-yl]-hept-5-enoic acid methyl ester 
• 65011-71-4 methyl 3-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-2,4-dideoxy-4-C-<(methoxycarbonyl)methyl>-α-D-ribo-hexopyranoside 
• 65011-75-8 Benzoic acid (2S,3S,4S,6S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-6-methoxy-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-4-yl ester 
• 65027-24-9 Benzoic acid (2R,3S,4S,6S)-2-((E)-(R)-3-hydroxy-oct-1-enyl)-6-methoxy-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-4-yl ester 
• 65011-79-2 Benzoic acid (2R,3S,4S,6S)-2-((E)-(S)-3-hydroxy-oct-1-enyl)-6-methoxy-3-((Z)-6-methoxycarbonyl-hex-2-enyl)-tetrahydro-pyran-4-yl ester 
• 65011-70-3 methyl 3-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-2,4-dideoxy-4-C--α-D-erythro-hexopyranoside 

Relevant academic research and scientific papers

An approach to the site-selective deoxygenation of hydroxy groups based on catalytic phosphoramidite transfer

Selective: The deoxygenation of simple and complex natural products employing a readily synthesized phosphoramidite and tetrazole catalysts can be executed as a two-step process, without the need to isolate intermediate deoxygenation precursors. Furthermore, a peptide-based tetrazole catalyst controls the site selectivity of deoxyerythromycin synthesis (see scheme), thus overcoming the notorious challenges with unprotected erythromycin A. Copyright