78153-83-0Relevant academic research and scientific papers
A NEW SYNTHESIS OF 2,3,4,6-TETRA-O-BENZYL-D-GLUCOPYRANOSYLIDENE ACETALS, USING TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE AS THE CATALYST
Horito, Shigeomi,Asano, Katsuji,Umemura, Kazuyuki,Hashimoto, Hironobu,Yoshimura, Juji
, p. 175 - 186 (2007/10/02)
The title compounds were synthesized by condensation of 2,3,4,6-tetra-O-benzyl-D-glucono-1,5-lactone with bis-O-(trimethylsilyl)-1,2-diols in the presence of trimethylsilyl trifluoromethanesulfonate as the catalyst.Application to cis- and trans-1,2-diols
A FACILE SYNTHESIS OF 2,3,4,6-TETRA-O-BENZYL-D-GLUCOPYRANOSYLIDENE ACETALS USING TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE CATALYST
Yoshimura, Juji,Horito, Shigeomi,Hashimoto, Hironobu
, p. 375 - 376 (2007/10/02)
The application of acetalization of aldehydes and ketones by alkoxysilanes in the presence of trimethylsilyl trifluoromethanesulfonate catalyst to lactones and di-O-trimethylsilyl-α-diols gave readily the corresponding spiro ortho esters.
