73045-57-5

Upstream product

• 84553-74-2 methyl 4,6-di-O-benzyl-2,3-O-isopropylidene-α-D-mannopyranoside 
• 347384-24-1 methyl 3-O-acetyl-2-O-acryloyl-4,6-di-O-benzyl-α-D-mannopyranoside 
• 20672-67-7 methyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 1454799-49-5 O-ethyl-S-[(((methyl 3,4,6-tri-O-benzyl-α-D-mannopyranos-2-yl)dimethylsilyl)methyl)]dithiocarbonate 
• 100-44-7 benzyl chloride 
• 63167-69-1 methyl 2,3-O-isopropylidene-α-D-mannopyranoside 
• 100-39-0 benzyl bromide 
• 347384-41-2 methyl 3-O-acetyl-4,6-di-O-benzyl-2-O-(bicyclo[2.2.1]hept-5-ene-2-carbonyl)-α-D-mannopyranoside 
• 13035-60-4 methyl 2,3:4,6-di-O-isopropylidene-α-D-mannopyranoside 
• 617-04-9 (2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol 

Downstream Products

• 78153-82-9 methyl 4,6-di-O-benzyl-2,3-O-(2,3,4,6-tetra-O-benzyl-D-glucopyranosylidene)-α-D-mannopyranoside 
• 82185-71-5 methyl 2-O-allyl-4,6-di-O-benzyl-α-D-mannopyranoside 
• 82185-72-6 methyl 3-O-allyl-4,6-di-O-benzyl-α-D-mannopyranoside 
• 116391-17-4 methyl 4,6-di-O-benzyl-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-α-D-mannopyranoside 
• 93636-34-1 Benzoic acid (2R,3R,4R,5S,6S)-3-benzyloxy-2-benzyloxymethyl-5-hydroxy-6-methoxy-tetrahydro-pyran-4-yl ester 
• 93636-33-0 Benzoic acid (2S,3S,4S,5S,6R)-5-benzyloxy-6-benzyloxymethyl-4-hydroxy-2-methoxy-tetrahydro-pyran-3-yl ester 
• 93636-35-2 C₃₅H₃₄O₈ 
• 102804-04-6 Toluene-4-sulfonic acid (2R,3R,4R,5S,6S)-3-benzyloxy-2-benzyloxymethyl-5-hydroxy-6-methoxy-tetrahydro-pyran-4-yl ester 
• 102804-03-5 Toluene-4-sulfonic acid (2S,3S,4S,5S,6R)-5-benzyloxy-6-benzyloxymethyl-4-hydroxy-2-methoxy-tetrahydro-pyran-3-yl ester 
• 102804-07-9 C₃₅H₃₈O₁₀S₂ 
• 88261-72-7 1,2,3-Tri-O-acetyl-4,6-di-O-benzyl-β-D-mannopyranose 
• 88261-71-6 1,2,3-Tri-O-acetyl-4,6-di-O-benzyl-α-D-mannopyranose 
• 102804-06-8 Benzoic acid (2R,3R,4S,5S,6S)-3-benzyloxy-2-benzyloxymethyl-6-methoxy-5-(toluene-4-sulfonyloxy)-tetrahydro-pyran-4-yl ester 
• 102804-05-7 Benzoic acid (2S,3S,4S,5R,6R)-5-benzyloxy-6-benzyloxymethyl-2-methoxy-4-(toluene-4-sulfonyloxy)-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

A tin-free regioselective radical de-o-benzylation by an intramolecular hydrogen atom transfer on carbohydrate templates

Radically selective: A remarkable 1,7-hydrogen atom transfer of a benzylic hydrogen atom to an O-silylmethylene radical initiates a regioselective de-O-benzylation of benzylated saccharides. The reaction terminates by an ionic mechanism and is general for hydroxy benzylated substrates having a variety of functional groups. Copyright

Highly diastereoselective Diels-Alder reactions of acrylic esters incorporated into a variety of hexopyranosides

The Diels-Alder reactions of a variety of hexopyranosides carrying an acrylic ester with cyclopentadiene were examined. Some acrylic esters provided the cycloaddition products carrying a norbornene carboxylate with a high level of diastereoselectivity. Plausible mechanisms are presented for the cases of a 4-O-acryloyl-6-deoxy-α-D-glucopyranosidic and 2-O-acryloyl-α-D-glucopyranosidic substrates. By reductive removal of the carbohydrate templates from the adducts, either 2S or 2R-enriched 5-norbornene-2-methanol were obtained.

Highly stereoselective Diels-Alder reactions achieved on some hexopyranosidic templates

The Diels-Alder reactions of some carbohydrate derivatives, as chiral acrylic esters, with cyclopentadiene proceed highly diastereoselectively to provide the adducts carrying a norbornene carboxylate. By reductive removal of the carbohydrate templates from the adducts, both 2S and 2R-enriched 5-norbornene-2-methanol are obtained.

Acceptor-Substrate Recognition by N-Acetylglucosaminyltransferase-V: Role of the Mannose Residue in βDGlcNAc(1->2)αDMan(1->6)βDGlcOR

βGlcNAc(1->2)αMan(1->6)βGlc-O(CH2)7CH3 (4) is an acceptor specific for N-acetylglucosaminyltransferase-V (GlcNAcT-V), a branching enzyme controlling the biosynthesis of cell-surface Asn-linked oligosaccharides.Three analogs of 4, where the central mannose

Synthesis of Standardized Building Blocks as a β-D-Mannosyl Donors with a Temporary Protection to be 3,6-Di-O-glycosyl Acceptors, for Constructing the Inner Core of Glycoproteins and Artificial Antigens

A synthetic scheme has been achieved for the core block of glycoproteins having D-mannose configuration, which is standardized to be a 3,6-di-O-glycosyl acceptor and react stereoselectively as a β-D-mannosyl donor.The synthesis was started by methyl 2,3-O