782472-45-1

Upstream product

• 116996-52-2 (2S)-4-O-(tert-butyldiphenylsilyl)butane-1,2,4-triol 
• 98-59-9 p-toluenesulfonyl chloride 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 146028-83-3 (2S)-1,2-O-isopropylidene-4-(tert-butyldiphenylsilyl)butane-1,2,4-triol 

Downstream Products

• 782472-46-2 1-(tert-butyl-diphenyl-silanyloxy)-octan-3-ol 
• 782472-47-3 tert-butyl-[3-(4-methoxy-benzyloxy)-octyloxy]-diphenyl-silane 
• 133218-79-8 (1'R,2'R)-1-O-tert-butyldiphenylsilyl-2-<2'-benzenesulfonyl-2'-(trimethylsilyl)methylcyclopropyl>ethan-1-ol 
• 133218-82-3 (3S,5R)-1-O-tert-butyldiphenylsilyl-5-benzenesulfonyl-6-(trimethylsilyl)hexane-1,3-diol 
• 133218-77-6 (3S,5S)-1-O-tert-butyldiphenylsilyl-5-benzenesulfonyl-6-(trimethylsilyl)hexane-1,3-diol 
• 133218-83-4 (3S,5R)-1-O-tert-butyldiphenylsilyl-3-O-methanesulfonyl-5-benzenesulfonyl-6-(trimethylsilyl)hexane-1,3-diol 
• 133218-78-7 (3S,5S)-1-O-tert-butyldiphenylsilyl-3-O-methanesulfonyl-5-benzenesulfonyl-6-(trimethylsilyl)hexane-1,3-diol 
• 120341-92-6 tert-Butyl-(2-{(2S,4S)-4-[(2S,4S)-4-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-1,5-dioxa-spiro[5.5]undec-2-ylmethyl]-1,5-dioxa-spiro[5.5]undec-2-yl}-ethoxy)-diphenyl-silane 
• 120341-89-1 (S)-1-{(2R,4S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-1,5-dioxa-spiro[5.5]undec-2-yl}-3-[2-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-[1,3]dithian-2-yl]-propan-2-ol 
• 120341-90-4 (S)-5-{(2R,4S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-1,5-dioxa-spiro[5.5]undec-2-yl}-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-hydroxy-pentan-2-one 
• 120341-91-5 (2R,4S)-1-{(2R,4S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-1,5-dioxa-spiro[5.5]undec-2-yl}-5-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-pentane-2,4-diol 
• 120341-93-7 (2S,4S,6S,8S,10S)-12-(tert-Butyl-diphenyl-silanyloxy)-dodecane-1,2,4,6,8,10-hexaol 
• 120341-85-7 (2S,4S,6S)-8-(tert-Butyl-diphenyl-silanyloxy)-octane-1,2,4,6-tetraol 
• 131522-39-9 Toluene-4-sulfonic acid (S)-3-{(2R,4S)-4-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-1,5-dioxa-spiro[5.5]undec-2-yl}-2-hydroxy-propyl ester 

Relevant academic research and scientific papers

A stereoselective synthesis of verbalactone-determination of absolute stereochemistry

A total synthesis of verbalactone has been achieved starting from l-malic acid. A total synthesis of verbalactone has been achieved starting from l-malic acid. The two appropriately protected acid and alcohol segments were prepared from l-malic acid and l

Enantioselective synthesis of the methylenecyclopropane derivative related to hypoglycine, from malic acid

Synthesis of (S)-methylenecyclopropaneacetic acid starting from L-(-)-malic acid, via (2S)-O-tert-butyldimethylsilyl-1,2-epoxybutan-4-ol and 1-O-tert-butyldiphenylsilyl-5-benzenesulfonyl-6-trimethylsilylhexane-1,3-diols as the key intermediates, is descri

A CONVERGENT GENERAL SYNTHETIC PROTOCOL FOR SYN-1,3-POLYOLS

A method for the stereoselective synthesis of syn-1,3-polyols using a chiral building block 1 is described.High syn-stereoselectivity in the reduction of β-hydroxy ketones was achieved using lithium aluminum hydride-lithium iodide.