78257-85-9Relevant academic research and scientific papers
THE PREPARATION AND REACTIONS OF 1-LITHIO-ALKYLAMINO-1-LITHIO-OXY-ALLENE DERIVATIVES
Adlington, R.M.,Barrett, A.G.M.
, p. 3935 - 3942 (2007/10/02)
The reaction of secondary α-keto-amide 2,4,6-tri-iso-propylbenzenesulphonylhydrazones with n-butyllithium generated, via a modified Shapiro reaction, the title carbanions -)NR1>.These reacted at carbon with deuterium oxide
Preparation and Reactions of 1-Lithio-oxy-1-lithio-amino-allene Derivatives
Adlington, Robert M.,Barrett, Anthony G. M.
, p. 65 - 67 (2007/10/02)
The title compounds Li+22CH=C=C(-O-)-N-R1>, prepared from secondary α-keto-amides via the Shapiro reaction, reacted at C-2 with aldehydes, acetone, and deuterium oxide; the products 2CH
