78283-48-4Relevant academic research and scientific papers
Polymeric nanoassembly of imine functionalized magnetite for loading copper salts to catalyze Henry and A3-coupling reactions
Rathod, Prakash B.,Kumar, K.S. Ajish,Athawale, Anjali A.,Pandey, Ashok K.
, (2021)
Poly(ethylenimine) was grafted on the magnetite (Fe3O4) nanoparticles, and subsequently reacted with different aldehydes to form the imine functionalities (Fe3O4-Imine NPs). Thus formed Fe3O4/su
Solvent and catalyst free route to 3-indolyl glycoconjugates: Synthesis of sugar tethered isoxazolines and isoxazoles from 3-indolyl nitroalkanes
Karthikeyan,Kumar, R. Senthil,Dheenkumar,Perumal, Paramasivan T.
, p. 27988 - 27997 (2014/07/21)
An expedient, solvent and catalyst free strategy for the synthesis of sugar based bis(indolyl)methanes and indolyl nitroalkanes has been developed. The protocol works well within a wide range of substrates, and tolerates various N/O protecting groups. The
Glycosynthase-Mediated Assembly of Xylanase Substrates and Inhibitors
Goddard-Borger, Ethan D.,Fiege, Brigitte,Kwan, Emily M.,Withers, Stephen G.
scheme or table, p. 1703 - 1711 (2012/06/29)
An exo-β-xylosidase mutant with glycosynthase activity was created to aid in the synthesis of xylanase substrates and inhibitors. Simple monosaccharides were easily elaborated into di-, tri- and tetrasaccharides by using this enzyme. Some products proved
Synthesis of densely functionalised C-glycosides by a tandem oxy Michael addition-Wittig olefination pathway
Senthil Kumar,Karthikeyan,Phani Kumar,Muralidharan,Perumal
experimental part, p. 457 - 461 (2010/04/24)
Wittig olefination of 5,6-dideoxy-5,6-anhydro-6-nitro-d-glucofuranose (5) triggered a concomitant cyclisation via oxy Michael addition of the C2-hydroxyl group resulting in the formation of C-vinyl glycosides with Z-olefinic geometry.
Orientation of the Addition of Dimethyl Phosphonate to 5,6-Dideoxy-6-nitro-D-hex-5-enofuranoses
Hanaya, Tadashi,Yamamoto, Hiroshi,Yamamoto, Hiroshi
, p. 1154 - 1156 (2007/10/02)
The addition of dimethyl phosphonate to six 5,6-dideoxy-6-nitro-D-hex-5-enofuranoses at 25 deg C in the presence of triethylamine preponderantly gave (5R)-adducts, whereas the same reaction at 100 deg C without a base yielded (5S)-adducts as the main products.
CHIRALE SYNTHESE VON (+)-LYCORICIDIN
Paulsen, Hans,Stubbe, Matthias
, p. 3171 - 3174 (2007/10/02)
The synthesis of (+)-lycoricidine from D-glucose is described.Addition of the carbanion 11 to the nitroolefine 10 yields the adduct 12+13, from which crystalline lactone 16 with muco-configuration in the cyclitol-ring can be isolated after hydrolysis and
