78303-39-6

Basic information

• Product Name: [1-(1-aci-Nitro-ethyl)-but-3-enyl]-benzene
• CAS NO: 78303-39-6
• Molecular Weight: 205.257
• Mol File: 78303-39-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [1-(1-aci-Nitro-ethyl)-but-3-enyl]-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [1-(1-aci-Nitro-ethyl)-but-3-enyl]-benzene(78303-39-6)
• EPA Substance Registry System: [1-(1-aci-Nitro-ethyl)-but-3-enyl]-benzene(78303-39-6)

Safety Data

• Hazardous Substances Data: 78303-39-6(Hazardous Substances Data)

Upstream product

• 705-60-2 1-phenyl-2-nitroprop-1-ene 
• 762-72-1 allyl-trimethyl-silane 

Downstream Products

• 26965-15-1 3-phenylhex-5-en-2-one 

Relevant articles and documents

REACTION OF ALLYLSILANE WITH α-NITRO OLEFIN AND ITS DEVELOPMENT TO SYNTHESIS OF CYCLOPENTENONE

Michael addition of allylsilane to α-nitro olefin in the presence of AlCl3 proceeded smoothly at low temperature to give unsaturated nitronic acid, which was converted into the γδ-enone using aqueous Ti (III).Transformation of the enone into the 1,4-diketone followed by the intramolecular aldol condensation with the latter provided a convenient new synthesis of cyclopentanone.