78348-96-6Relevant academic research and scientific papers
Electrophilic amination of diorganozinc reagents by oxaziridines
Ghoraf, Mohammed,Vidal, Jo?lle
scheme or table, p. 7383 - 7385 (2009/05/07)
Electrophilic amination of organozinc reagents by oxaziridines has been studied. Diorganozinc reagents R2Zn (R = alkyl or aryl) react with N-Boc oxaziridine to afford N-Boc protected primary amines BocNHR in moderate to good yields. No additive
Selectivities in the Reactions of Alkyl-, Aryl- and Heterosubstituted Organotitanium Compounds
Weidmann, Beat,Widler, Leo,Olivero, Alan G.,Maycock, Christopher D.,Seebach, Dieter
, p. 357 - 361 (2007/10/02)
Solutions of the title compounds R-Ti(OR')3 (1) are generally available from organolithium (or magnesium) derivatives according to equation 1.It is shown (table 1) that some heterosubstituted organotitanium compounds are more stable thermally than their lithium counterparts.The reagents 1 are highly selective carbonylophiles (Tables 1 and 2), their reactivity can be modified by variation of the R'O-group (Table 3) and with the chiral (S)-2-methyl-1-butoxy group an enantioselective addition can be achieved.
