78361-47-4Relevant articles and documents
Synthesis, Characterization and Thermal Studies on Ru(III), Rh(III), Ir(III), Pd(II), Pt(II) and Os(IV) Dithiocarbamates
Kumar, S.,Kaushik, N. K.
, p. 512 - 515 (2007/10/02)
N-(ethyl,m-tolyl)dithiocarbamato complexes of Ru(III), Rh(III), Pd(II), Os(IV), Ir(III) and Pt(II) have been prepared in aqueous medium and characterized on the basis of elemental analyses, molecular weight, conductance, magnetic moment and spectral (vibrational and electronic) studies.All the complexes are non-conducting monomeric species in which the dithiocarbamate ligand acts as a bidentate ligand.Except the Ru(III) complex, all the other complexes are diamagnetic.Ru(III), Rh(III) and Ir(III) complexes are octahedral whereas Pd(II), and Pt(II) complexes are square-planar.Os(IV) complex is seven-coordinated.Thermogravimetric study of these compounds under nitrogen atmosphere has also been carried out.