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Z-<3-2H>-allyl alcohol, also known as (Z)-3-2H-allyl alcohol, is a deuterated organic compound with the molecular formula C3H5OD. It is a chiral molecule, meaning it has a non-superimposable mirror image. The compound features a double bond between the first and second carbon atoms, with the third carbon atom bearing a hydroxyl group and a deuterium atom (2H, or D). This deuterium atom replaces one of the hydrogen atoms in the allyl alcohol molecule, making it a valuable tool in various chemical and biological studies, particularly in isotope labeling and kinetic isotope effect experiments. The compound is used to investigate reaction mechanisms, study the behavior of enzymes, and understand the impact of isotopic substitution on chemical reactivity.

78370-35-1

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78370-35-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 78370-35-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,8,3,7 and 0 respectively; the second part has 2 digits, 3 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 78370-35:
(7*7)+(6*8)+(5*3)+(4*7)+(3*0)+(2*3)+(1*5)=151
151 % 10 = 1
So 78370-35-1 is a valid CAS Registry Number.

78370-35-1Upstream product

78370-35-1Relevant academic research and scientific papers

Cyclization of 1,6-enynes catalyzed by gold nanoparticles supported on TiO2: Significant changes in selectivity and mechanism, as compared to homogeneous Au-catalysis

Gryparis, Charis,Efe, Christina,Raptis, Christos,Lykakis, Ioannis N.,Stratakis, Manolis

, p. 2956 - 2959 (2012)

Gold nanoparticles supported on TiO2 (1.2 mol %) catalyze, for the first time under heterogeneous conditions, the cycloisomerization of a series of 1,6-enynes in high yields. In several cases, the product selectivity differs significantly as compared to homogeneous Au(I)-catalysis. Based on product analysis and stereoisotopic studies it is proposed that the major or exclusive pathway involves a 5-exo cyclization mode to form stereoselectively gold cyclopropyl carbenes that undergo a single cleavage pathway, in contrast to homogeneous Au-catalysis where the double cleavage pathway operates substantially.

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