784182-27-0Relevant academic research and scientific papers
Group-selective ring-closing enyne metathesis: Concentration-dependent selectivity profile of alkynylsilyloxy-tethered dienynes
Maifeld, Sarah V.,Miller, Reagan L.,Lee, Daesung
, p. 12228 - 12229 (2007/10/03)
Highly group-selective ring-closing metathesis of alkynylsilyloxy-tethered dienynes was achieved by using Grubbs first- and second-generation catalyst. The remarkable selectivity increase at higher concentration for differentiating between two alkene moie
Efficient synthesis of alkynylsilyl ethers and silaketals via base-induced alkynylsilane alcoholysis
Grimm, Jonathan B.,Lee, Daesung
, p. 8967 - 8970 (2007/10/03)
The efficient silylation of alcohols with di- and trialkynylsilanes was achieved under base-catalyzed conditions to afford alkynyl silyl ethers and symmetrical alkynyl silaketals in good yield. A selective alcoholysis of dialkynyl silyl ethers to mixed si
