78499-87-3Relevant academic research and scientific papers
Metal Complexes derived from the o-Xylylidene Ligand, o-C6H4(CH2-)2, and the X-Ray Crystal and Molecular Structure of the Metallocycle >
Lappert, Michael F.,Martin, Tony R.
, p. 476 - 477 (1980)
From the new di-Grignard reagent o-C6H4(CH2MgCl)2 (i) the thermally stable metallobenzocyclopentenes (R = Me3Si and M = Ti, Zr, or Hf; or R = H and M = Ti or Zr ) and , (ii) the η1-diacylHf(η-C5H4SiMe3)2
Magnesium Anthracene: An Alternative to Magnesium in the High Yield Synthesis of Grignard Reagents
Raston, Colin L.,Salem, Geoffrey
, p. 1702 - 1703 (1984)
Benzylic type di-Grignard reagents (2)-(5) and the mono-Grignard reagent (6) have been prepared by treating the appropriate organic chloride, for (2)-(6), or bromide, for (3) and (4), with magnesium anthracene in tetrahydrofuran in yields of, respectively, 92-96percent, and 60 and 84percent.
Method of manufacturing phosphine compound
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Page column 4, (2008/06/13)
A method of preparing a compound (I) of general formula (R3—C)2P—L1—X—L2—P—(C—R3)2, in which R is independently a pendant, optionally substituted, organic group through which the group is l
Indenyl compounds for the polymerization of olefins
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Page column 23, (2010/01/30)
Indenyl compound of formula (1) wherein: M is a transition metal from the lanthanides or from group 3, 4, 5 or 6 of the Periodic System of Elements, Q is an anionic ligand to M, k is the number of Q groups, R is a bridging group and Z and X are substituents, wherein R contains at least one sp2-hybridized carbon atom that is bonded to the indenyl group at the 2-position with the exclusion of Ti(deshydronorbiphenacene) dichloride.
Polymer supporeted 'Magnesium(anthracene)': Effective in Forming Benzylic Grignard Reagents (via Electron Transfer Reactions)
Harvey, Stephen,Raston, Colin L.
, p. 652 - 653 (2007/10/02)
A polymer supported 'magnesium(anthracene)' (4) has been prepared from the reaction in tetrahydrofuran (thf) of (1) with polystyrene bearing -9-CH2SiMe2(C14H9) groups (3); the green paramagnetic solid, containing dianion radical anion anthracene sites, yields Grignard reagents (>90percent) with benzylic halides in thf via electron transfer reactions, as does the model compound for the dianion sites, viz. (thf)2> (6).
