Magnesium Anthracene: An Alternative to Magnesium in the High Yield Synthesis of Grignard Reagents

DOI: 10.1039/c39840001702

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1702 - 1703 (1984)

Update date:2022-08-30

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Authors:

Raston, Colin L.

Salem, Geoffrey

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Article abstract of DOI:10.1039/c39840001702

Benzylic type di-Grignard reagents (2)-(5) and the mono-Grignard reagent (6) have been prepared by treating the appropriate organic chloride, for (2)-(6), or bromide, for (3) and (4), with magnesium anthracene in tetrahydrofuran in yields of, respectively, 92-96percent, and 60 and 84percent.

Full text of DOI:10.1039/c39840001702

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