78506-98-6Relevant academic research and scientific papers
On the decarboxylation of 2-methyl-1-tetralone-2-carboxylic acid-oxidation of the enol intermediate by triplet oxygen
Riahi, Abdelkhalek,Muzart, Jacques,Abe, Manabu,Hoffmann, Norbert
, p. 2245 - 2249 (2013/09/24)
The formation of 2-methyl-1-tetralone from the metal-free and base-free decarboxylation of 2-methyl-1-tetralone-2-carboxylic acid involves 2-methyl-3,4-dihydro-1-naphthol as an intermediate. The reaction of this enol with atmospheric oxygen leads to 2-hyd
Oxidation of 2-substituted cycloalkanones with cerium(IV) sulfate tetrahydrate in alcohols and acetic acid
He, Liangyou,Horiuchi, C. Akira
, p. 2515 - 2521 (2007/10/03)
The reaction of 2-substituted cycloalkanones with cerium(IV) sulfate tetrahydrate (CS) in alcohols and acetic acid gave the corresponding alkyl esters of oxo acids (80-96%) and oxo acids (78-96%), respectively, by oxidative cleavage of the C(R).C=O bond. In the case of 2-iodocycloalkanones in methanol, the dimethyl ester was obtained in good yield. A treatment of 5α-cholestan-3-one with CS in methanol produced 2-acetal 3-ester of 2,3-seco derivative in good yield. The effects of cerium(IV) and copper(II) salts are also discussed.
STUDIES ON THE TERPENOIDS AND RELATED ALICYCLIC COMPOUNDS XXII STEREOCHEMICAL STUDY ON THE ANGULAR HYDROXYLATION OF POLYCYCLIC KETONES USING BENZENESELENINIC ANHYDRIDE
Yamakawa, Koji,Satoh, Tsuyoshi,Ohba, Nobuyuki,Sakaguchi, Reiji,Takita, Satoshi,Tamura, Nobuhiko
, p. 473 - 480 (2007/10/02)
Introduction of an OH group to the tertiary carbon of simple ketones (1, 2 and 6), furanoeremophilane-type ketones (12-19), and tricyclic ketones (20-22) by the use of benzeneseleninic anhydride is described. 10β-Hydroxy compounds were obtained in the case of 12-14, and 20-22. 10α-Hydroxy compounds were obtained in the case of 15 and 16.In the hydroxylation reaction of polycyclic ketones using benzeneseleninic anhydride, the results suggest that the thermodynamically more stable product was usually produced as the major product.
