78506-98-6Relevant articles and documents
On the decarboxylation of 2-methyl-1-tetralone-2-carboxylic acid-oxidation of the enol intermediate by triplet oxygen
Riahi, Abdelkhalek,Muzart, Jacques,Abe, Manabu,Hoffmann, Norbert
, p. 2245 - 2249 (2013/09/24)
The formation of 2-methyl-1-tetralone from the metal-free and base-free decarboxylation of 2-methyl-1-tetralone-2-carboxylic acid involves 2-methyl-3,4-dihydro-1-naphthol as an intermediate. The reaction of this enol with atmospheric oxygen leads to 2-hyd
STUDIES ON THE TERPENOIDS AND RELATED ALICYCLIC COMPOUNDS XXII STEREOCHEMICAL STUDY ON THE ANGULAR HYDROXYLATION OF POLYCYCLIC KETONES USING BENZENESELENINIC ANHYDRIDE
Yamakawa, Koji,Satoh, Tsuyoshi,Ohba, Nobuyuki,Sakaguchi, Reiji,Takita, Satoshi,Tamura, Nobuhiko
, p. 473 - 480 (2007/10/02)
Introduction of an OH group to the tertiary carbon of simple ketones (1, 2 and 6), furanoeremophilane-type ketones (12-19), and tricyclic ketones (20-22) by the use of benzeneseleninic anhydride is described. 10β-Hydroxy compounds were obtained in the case of 12-14, and 20-22. 10α-Hydroxy compounds were obtained in the case of 15 and 16.In the hydroxylation reaction of polycyclic ketones using benzeneseleninic anhydride, the results suggest that the thermodynamically more stable product was usually produced as the major product.