78569-34-3

Basic information

• Product Name: methyl erythro-2,3-diphenyl-3-(N-phenylamino)propionate
• CAS NO: 78569-34-3
• Molecular Weight: 331.414
• Mol File: 78569-34-3.mol

Chemical Properties

• CAS DataBase Reference: methyl erythro-2,3-diphenyl-3-(N-phenylamino)propionate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl erythro-2,3-diphenyl-3-(N-phenylamino)propionate(78569-34-3)
• EPA Substance Registry System: methyl erythro-2,3-diphenyl-3-(N-phenylamino)propionate(78569-34-3)

Safety Data

• Hazardous Substances Data: 78569-34-3(Hazardous Substances Data)

Upstream product

• 32346-06-8 (E)-(1-methoxy-2-phenylvinyloxy)trimethylsilane 
• 100-52-7 benzaldehyde 
• 62-53-3 aniline 
• 1750-36-3 (E)-N-benzylidenebenzenamine 
• 101-41-7 benzeneacetic acid methyl ester 
• 40195-27-5 (1-methoxy-2-phenylvinyloxy)trimethylsilane 

Relevant articles and documents

Bronsted Acid-Catalyzed Mannich-Type Reactions in Aqueous Media

HBF4-catalyzed Mannich-type reaction of silyl enolates with aldimines took place smoothly in aqueous organic solvent to afford β-aminocarbonyl compounds in high yields. The HBF4-catalyzed Mannich-type reaction also proceeded smoothly

Stereoselective synthesis of syn-β-amino esters using the TiCl 4/R3N reagent system

The reactions of benzaldehyde imines and esters with the TiCl 4/R3N reagent system give syn-β-amino esters as the major products in 38-87% yields.

One-pot Mannich-type reaction in water: HBF4 catalyzed condensation of aldehydes, amines, and silyl enolates for the synthesis of β-amino carbonyl compounds

HBF4 catalyzed Mannich-type reactions of aldehydes, amines, and silyl enolates took place smoothly in water in the presence of a surfactant to afford β-amino carbonyl compounds in high yields. Thieme Stuttgart.

DIASTEREOSELECTION IN TRIMETHYLSILYL TRIFLUOROMETHANESULPHONATE CATALYZED REACTION OF SILYL KETENE ACETALS WITH IMINES

The trimethylsilyl trifluoromethanesulphonate catalyzed condensation of silyl ketene acetals with imines afforded β-amino esters with prevalent anti relative diastereoselectivity (up to 100percent).Some anti β-amino esters have been then cyclized to trans