78601-29-3Relevant academic research and scientific papers
Asymmetric allylic substitution reactions of 2-substituted 2-cycloalkenyl carbonates using 9-PBN coordinated palladium
Hamada, Yasumasa,Sakaguchi, Ken-Ei,Hatano, Keiichiro,Hara, Osamu
, p. 1297 - 1299 (2001)
2-Substituted 2-cycloalkenyl carbonates are suitable substrates for asymmetric allylic substitution reaction using 9-PBN coordinated palladium, producing the allylic substituted products with high enantiomeric excess.
A convenient procedure for smooth palladium-catalyzed allylic alkylation by sodium dimethyl malonate and cyclopentadienide. A new synthesis of allylic substituted cyclopentadienes.
Fiaud,Malleron
, p. 4437 - 4440 (2007/10/02)
The use of the Pd(dba)1 1 dba stands for dibenzylideneacetone2/dpe catalytic system in allylic alkylation allows sodium dimethyl malonate to react with allylic acetates at room temperature. According to this procedure, a novel synthe
