78607-01-9Relevant academic research and scientific papers
THE REARRANGEMENT OF SOME 2-SUBSTITUTED-4-BROMO-2,5-DINITRO-6-HYDROXY-3,6-DIMETHYLCYCLOHEX-3-EN-1-ONES
Bates, P. A.,Gray, M. J.,Hartshorn, M. P.,Houng Tuong Ing.,Richards, K. E.,Robinson, W. T.
, p. 1279 - 1280 (1981)
In chloroform at 20 deg C, or in tetrachloroethylene at 120 deg C, the title compounds(1) rearrange to give the α-diketone(2), the structure of which was determined by X-ray crystal structure analysis; a possible rearrangement mechanism is outlined.
