Tetrahedron Letters p. 1279 - 1280 (1981)
Update date:2022-08-04
Topics:
Bates, P. A.
Gray, M. J.
Hartshorn, M. P.
Houng Tuong Ing.
Richards, K. E.
Robinson, W. T.
In chloroform at 20 deg C, or in tetrachloroethylene at 120 deg C, the title compounds(1) rearrange to give the α-diketone(2), the structure of which was determined by X-ray crystal structure analysis; a possible rearrangement mechanism is outlined.
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