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Vanadium, tris(phenylmethyl)-, also known as tris(benzyl)vanadium, is an organometallic compound with the chemical formula C18H15V. It is a dark red-brown solid that is sensitive to air and moisture. Vanadium, tris(phenylmethyl)- is formed by the coordination of three benzyl ligands (C6H5CH2-) to a central vanadium atom. Tris(phenylmethyl)vanadium is an important precursor in the synthesis of various vanadium-containing materials and catalysts, particularly in the field of homogeneous catalysis. It is also used in the production of vanadium-based alloys and as a reagent in organic synthesis. Due to its sensitivity to air and moisture, it is typically handled under an inert atmosphere or in a glovebox.

78628-01-0

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78628-01-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 78628-01-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,8,6,2 and 8 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 78628-01:
(7*7)+(6*8)+(5*6)+(4*2)+(3*8)+(2*0)+(1*1)=160
160 % 10 = 0
So 78628-01-0 is a valid CAS Registry Number.

78628-01-0Downstream Products

78628-01-0Relevant academic research and scientific papers

SYNTHESIS AND PROPERTIES OF COVALENT TRI- AND TETRAVALENT VANADIUM

Razuvaev, G.A.,Latyaeva, V.N.,Vyshinskaya, L.I.,Drobotenko, V.V.

, p. 169 - 182 (1981)

Reactions of VCl3*3THF with RMgX (R = Ph, CH2SiMe3, C6F5) in various ratios have been studied.The stable compounds R3V*THF (R = CH2SiMe3, C6F5) were obtained.The chemical properties of R3V*THF, R4V*2L (R = CH2Ph, L = Et2O; R = C6F5, L = THF) and (Me3SiCH2)4V were investigated.Cleavage of the vanadium-carbonium ?-bond occurs in reactions with H2O, HCl and HgCl2.The insertion of carbon dioxide into the vanadium-carbon ?-bond was investigated.A scheme for the derivatives of tri- and tetravalent vanadium is proposed.Oxidative addition to (C6F5)3V*THF by Ph3CCl and VCl3*3THF was also studied.

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