Journal of Organometallic Chemistry p. 169 - 182 (1981)
Update date:2022-08-05
Topics:
Razuvaev, G.A.
Latyaeva, V.N.
Vyshinskaya, L.I.
Drobotenko, V.V.
Reactions of VCl3*3THF with RMgX (R = Ph, CH2SiMe3, C6F5) in various ratios have been studied.The stable compounds R3V*THF (R = CH2SiMe3, C6F5) were obtained.The chemical properties of R3V*THF, R4V*2L (R = CH2Ph, L = Et2O; R = C6F5, L = THF) and (Me3SiCH2)4V were investigated.Cleavage of the vanadium-carbonium ?-bond occurs in reactions with H2O, HCl and HgCl2.The insertion of carbon dioxide into the vanadium-carbon ?-bond was investigated.A scheme for the derivatives of tri- and tetravalent vanadium is proposed.Oxidative addition to (C6F5)3V*THF by Ph3CCl and VCl3*3THF was also studied.
Ningbo Tide Imp. & Exp. Co., Ltd.
Contact:+86-571-8993 7933; +86-571-8993 6453
Address:7/F Anno Domini Building, Tower South, 8 Qiu Shi Road,Hangzhou,China.
website:http://www.arromax.com
Contact:+86-0512-62959601 skype:aimmezhang
Address:Suite 401, Bldg A3, 218 Xinghu St.Suzhou Industrial Park 215123, P.R. China
Contact:86-510-82853889
Address:Rm.3732, No.18-2,Yonghe Rd.,Wuxi,Jiangsu,214023,China
Taixing Shenfeng Chemical Co., Ltd.
Contact:+86-523-87117033, 87117666
Address:4# Yinsanlu, Huangqiao town, Taixing, Jiangsu, China.
Beijing ZhongDaXinHe Chemical Product Co.,Ltd(expird)
Contact:010-52876516
Address:tongzhoubeiyuan
Doi:10.1016/S0040-4039(01)93298-8
(1981)Doi:10.1021/ol049026b
(2004)Doi:10.1246/cl.2004.1174
(2004)Doi:10.3797/scipharm.2006.74.85
(2006)Doi:10.1021/acscatal.5b00314
(2015)Doi:10.1055/s-2006-951543
(2006)
