78632-12-9

Upstream product

• 120-20-7 2-(3,4-dimethoxyphenyl)-ethylamine 
• 1655-07-8 ethyl 2-oxocyclohexane carboxylate 
• 4746-93-4 1,4-dioxaspiro[4.5]decane-6-carboxylic acid 
• 78632-11-8 N-<2-(3,4-Dimethoxyphenyl)ethyl>-2,2-ethylendioxy-1-cyclohexancarboxamid 

Relevant academic research and scientific papers

Microwave-assisted wolff rearrangement of cyclic 2-diazo-1,3-diketones: An eco-compatible route to α-carbonylated cycloalkanones

(Chemical Equation Presented) The microwave-assisted Wolff rearrangement of cyclic 2-diazo-1,3-diketones performed in the presence of a stoichiometric amount of alcohol, amine, or thiol is an efficient, user, and environmentally friendly synthetic protocol for the synthesis of α-carbonylated cycloalkanones. This approach proves superior to existing protocols in scope and eco-compatibility.

A Reversible Rearrangement of the trans-Erythrinane Ring System, IV. Ivestigations Concerning the Reaction Mechanism

The labelled β-lactame carboxylic acid 10a is prepared via the diol-A 7.The products of thermal decarboxylation 11a and 12a include the whole activity of the original carboxylic acid 10a.On the other hand, decarboxylation of 10a with sulfuric ac