78640-25-2Relevant academic research and scientific papers
An unexpected Prins desymmetrisation reaction driven by silyl migration
Butters, Michael,Elliott, Mark C,Hill-Cousins, Joseph T.
experimental part, p. 113 - 125 (2012/10/08)
Prins desymmetrisation reactions of cyclohexa-1,4-diene derivatives have been investigated as a route to the core of the cladiellin diterpenes. During the course of this work, we observed the formation of a partially-reduced benzofuran 18, which is clearl
Organometallic Compounds in Organic Synthesis. Part 14. Tricarbonyliron as Lateral Control Group in the Selective Alkaline Hydrolysis of some Cyclohexa-1,3-diene Carboxylic Esters
Bandara, B. M. Ratnayake,Birch, Arthur J.,Raverty, Warwick D.
, p. 1763 - 1770 (2007/10/02)
Alkaline hydrolyses of a number of methoxycarbonyl derivatives of cyclohexa-1,3-diene-Fe(CO)3 have been used as indices of steric and electronic effects on reactivities of the ester groups.A β-CO2Me or a 1-CO2Me group is resistant to hydrolysis for steric
