78679-97-7Relevant academic research and scientific papers
Temperature and Pressure Dependences of Thermal Cis-to-Trans Isomerization of Azobenzenes Which Evidence an Inversion Mechanism
Asano, Tsutomu,Okada, Toshio,Shinkai, Seiji,Shigematsu, Kazuyoshi,Kusano, Yumiko,Manabe, Osamu
, p. 5161 - 5165 (1981)
The mechanism of thermal cis-to-trans isomerization of azobenzene derivatives (rotation versus inversion) is discussed. cis-1 has an azobenzene covalently bridged to an aza crown ether, and rotation of the benzene rings is sterically restricted.The pressu
ON THE ROTATION VERSUS THE INVERSION MECHANISM IN THE THERMAL ISOMERIZATION OF CIS-AZOBENZENES
Shinkai, Seiji,Kusano, Yumiko,Shigematsu, Kazuyoshi,Manabe, Osamu
, p. 1303 - 1306 (2007/10/02)
The thermal cis-to-trans isomerization of an azobenzene covalently-bridged to azacrown ether occurs via the inversion mechanism, and the rotational mechanism is not allowed owing to the rigid ring structure.By using the "standard" azobenzene, it was demon
Photoresponsive Crown Ethers. 1. Cis-Trans Isomerism of Azobenzene as a Tool to Enforce Conformational Changes of Crown Ethers and Polymers
Shinkai, Seiji,Nakaji, Takahiro,Nishida, Yoshihiro,Ogawa, Toshiyuki,Manabe, Osamu
, p. 5860 - 5865 (2007/10/02)
An azobenzene-bridged crown ether (2) and a polymer containing both crown ether unit and azobenzene unit (4) were synthesized. 2 bridged with trans-azobenzene (trans-2) bound an ammonium cation (5) and methyl orange salts of Li+ and Na+/s
