Temperature and Pressure Dependences of Thermal Cis-to-Trans Isomerization of Azobenzenes Which Evidence an Inversion Mechanism

DOI: 10.1021/ja00407a034

Source and publish data:

Journal of the American Chemical Society p. 5161 - 5165 (1981)

Update date:2022-08-02

Topics:

Authors:

Asano, Tsutomu

Okada, Toshio

Shinkai, Seiji

Shigematsu, Kazuyoshi

Kusano, Yumiko

Manabe, Osamu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00407a034

The mechanism of thermal cis-to-trans isomerization of azobenzene derivatives (rotation versus inversion) is discussed. cis-1 has an azobenzene covalently bridged to an aza crown ether, and rotation of the benzene rings is sterically restricted.The pressu

Full text of DOI:10.1021/ja00407a034

Products guided by the article

Product name:trans-3,3'-bis(morpholinocarbonyl)azobenzene

Cas No:78679-97-7

R&D Labs maybe for 78679-97-7

Shanghai Yuanye Bio-Technology Co., Ltd.

website:http://www.shyuanye.com

Contact:+86-21-61845781

Address:Building 6, No. 465, Changta Road,Songjiang District,Shanghai,China
NINGBO PANGS CHEM INT’L CO.,LTD.

Contact:+86-574-27666845

Address:FLOOR 21,BUILDING NO.11,XIN TIAN DI,NO.689 SHI JI ROAD,NINGBO CHINA
SHANGHAI T&W PHARMACEUTICAL CO., LTD.

website:http://www.trustwe.com

Contact:+86-21-61551611

Address:601, No. 1, 2277 Nong, Zu Chongzhi Road, Zhangjiang Hightech. Park, Pudong
NingBO Hong Xiang Biochem.Co.Ltd

website:http://www.hxbiochem.com

Contact:0574-66003444

Address:Ning Bo Bei Lun
Hangzhou Dingyan Chem Co., Ltd

website:http://www.dingyanchem.com

Contact:86-571-87157530-8002

Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004

Relevant to this article

Novel 1,3,5-triazine derivatives exert potent anti-cervical cancer effects by modulating Bax, Bcl2 and Caspases expression

Doi:10.1111/cbdd.13133
(2018)
Novel polyaromatic ionomers with large hydrophilic domain and long hydrophobic chain targeting at highly proton conductive and stable membranes

Doi:10.1039/c1jm10950b
(2011)
The Synthesis, Structural Characterization and Conformational Analysis of (1,3-Bis(2-methyl-4-diethylaminophenyl)imidazolidin-2-ylidene)chloro(1, 5-cyclooctadiene)rhodium(I)

Doi:10.1515/znb-2005-0804
(2005)
Halogen and chalcogen cation pools stabilized by DMSO. Versatile reagents for alkene difunctionalization

Doi:10.1021/ja4092648
(2013)
Analysis of an asymmetric addition with a 2:1 mixed lithium amide/n-butyllithium aggregate

Doi:10.1021/jo800592d
(2008)
Formation of functionalized 2H-azirines through phio-mediated trifluoroethoxylation and azirination of enamines

Doi:10.1021/ol4030716
(2013)

Article Doi