Temperature and Pressure Dependences of Thermal Cis-to-Trans Isomerization of Azobenzenes Which Evidence an Inversion Mechanism

DOI: 10.1021/ja00407a034

Source and publish data:

Journal of the American Chemical Society p. 5161 - 5165 (1981)

Update date:2022-08-02

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Authors:

Asano, Tsutomu

Okada, Toshio

Shinkai, Seiji

Shigematsu, Kazuyoshi

Kusano, Yumiko

Manabe, Osamu

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Article abstract of DOI:10.1021/ja00407a034

The mechanism of thermal cis-to-trans isomerization of azobenzene derivatives (rotation versus inversion) is discussed. cis-1 has an azobenzene covalently bridged to an aza crown ether, and rotation of the benzene rings is sterically restricted.The pressu

Full text of DOI:10.1021/ja00407a034

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