Temperature and Pressure Dependences of Thermal Cis-to-Trans Isomerization of Azobenzenes Which Evidence an Inversion Mechanism

DOI: 10.1021/ja00407a034

Source and publish data:

Journal of the American Chemical Society p. 5161 - 5165 (1981)

Update date:2022-08-02

Topics:

Authors:

Asano, Tsutomu

Okada, Toshio

Shinkai, Seiji

Shigematsu, Kazuyoshi

Kusano, Yumiko

Manabe, Osamu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00407a034

The mechanism of thermal cis-to-trans isomerization of azobenzene derivatives (rotation versus inversion) is discussed. cis-1 has an azobenzene covalently bridged to an aza crown ether, and rotation of the benzene rings is sterically restricted.The pressu

Full text of DOI:10.1021/ja00407a034

Products guided by the article

Product name:trans-3,3'-bis(morpholinocarbonyl)azobenzene

Cas No:78679-97-7

R&D Labs maybe for 78679-97-7

Dayang Chem (Hangzhou) Co.,Ltd.

website:http://www.dycnchem.com

Contact:+86-571-88938639

Address:9/F, Unit 2 Changdi Torch Building, 259# WenSan Road, Xihu District, Hangzhou City 310012, P.R.China
Hefei TNJ chemical industry co.,ltd

website:https://www.tnjchem.com

Contact:+86-551-65418695

Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China
Beijing Cooperate Pharmaceutical Co.,Ltd

website:http://www.cooperate-pharm.com/

Contact:86-01060279497

Address:No.507,Building 4,Tianhua Street, Biomedicine industrial Base
Hangzhou Ledun Technology Co.,Ltd.

Contact:86-571-18767088918

Address:No.6 street,XiaSha,Hangzhou,China.
China Synchem Technology Co.,Ltd

website:http://www.cnsynchem.com

Contact:+86-0552-4929311

Address:No.217 Daqing Road

Relevant to this article

Novel 1,3,5-triazine derivatives exert potent anti-cervical cancer effects by modulating Bax, Bcl2 and Caspases expression

Doi:10.1111/cbdd.13133
(2018)
Novel polyaromatic ionomers with large hydrophilic domain and long hydrophobic chain targeting at highly proton conductive and stable membranes

Doi:10.1039/c1jm10950b
(2011)
The Synthesis, Structural Characterization and Conformational Analysis of (1,3-Bis(2-methyl-4-diethylaminophenyl)imidazolidin-2-ylidene)chloro(1, 5-cyclooctadiene)rhodium(I)

Doi:10.1515/znb-2005-0804
(2005)
Halogen and chalcogen cation pools stabilized by DMSO. Versatile reagents for alkene difunctionalization

Doi:10.1021/ja4092648
(2013)
Analysis of an asymmetric addition with a 2:1 mixed lithium amide/n-butyllithium aggregate

Doi:10.1021/jo800592d
(2008)
Formation of functionalized 2H-azirines through phio-mediated trifluoroethoxylation and azirination of enamines

Doi:10.1021/ol4030716
(2013)

Article Doi