78727-63-6

Upstream product

• 14897-51-9 Benzyl 3,4-O-isopropylidene-β-D-galactopyranoside 
• 100-39-0 benzyl bromide 

Downstream Products

• 108678-06-4 (3aS,4R,6R,7R,7aS)-6-Benzyloxy-4-benzyloxymethyl-2,2-dimethyl-7-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-[1,3]dioxolo[4,5-c]pyran 
• 108678-07-5 (3aS,4R,6R,7R,7aS)-6-Benzyloxy-4-benzyloxymethyl-2,2-dimethyl-7-((2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-[1,3]dioxolo[4,5-c]pyran 
• 104707-07-5 benzyl 6-O-benzyl-3,4-O-isopropylidene-2-O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-β-D-galactopyranoside 
• 78727-73-8 benzyl 3,6-di-O-benzyl-β-D-galactopyranoside 
• 57783-81-0 Benzyl 2,3,6-tri-O-benzyl-β-D-galactopyranoside 
• 78727-67-0 benzyl 6-O-benzyl-β-D-galactopyranoside 
• 104707-05-3 benzyl 2-O-benzyl-3,4-O-isopropylidene-2-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-β-D-galactopyranoside 
• 78727-65-8 benzyl 2-O-acetyl-6-O-benzyl-3,4-O-isopropylidene-β-D-galactopyranoside 

Relevant academic research and scientific papers

Silyl group migration in 1-O-silyl protected sugars-convenient synthesis of 2-O-unprotected sugars

Reaction of 2-O-unprotected 1-9-silyl-protected D-glucose and D-galactose derivatives 5a-d with benzyl bromide in the presence of sodium hydride as the base afforded 1-O-benzyl 2-O-silyl derivatives 6aα/β - 6dα/β. Thus, prior to anomeric O-benzylation, t

A Mild Procedure for the Regiospecific Benzylation and Allylation of Polyhydroxy-compounds via their Stannylene Derivatives in Non-polar Solvents

The reactions of benzyl and allylbromides on the stannylene derivatives of polyhydroxy-compounds, which normally proceed only at insignificant speed in refluxing benzene solution, are greatly accelerated in the presence of quaternary ammonium halides.Thes