78786-68-2

Upstream product

• 52786-52-4 4-chloro-N-(2,2,2-trifluoro-1-trifluoromethyl-ethylidene)-benzamide 
• 87574-77-4 2-(4-Chlorophenyl)-5,5-difluoro-4-(trifluoromethyl)-2-oxazoline 
• 78786-67-1 4-(Difluormethylen)-5,5-difluor-2-(4-chlorphenyl)-Δ²-oxazolin 
• 54289-98-4 N-<1-(Chlordifluormethyl)-2,2-difluorvinyl>-4-chlor-benzimidoylchlorid 
• 116177-78-7 N-<2,2-Difluoro-1-(trifluoromethyl)vinyl>-4-chlorobenzamid 

Downstream Products

• 116672-06-1 N'-[2-(4-Chloro-phenyl)-4-trifluoromethyl-oxazol-5-yl]-N,N-dimethyl-hydrazine 
• 83081-33-8 2-(4-Chlorphenyl)-5-morpholino-4-(trifluormethyl)oxazol 

Relevant academic research and scientific papers

UEBER DAS SYNTHESEPOTENTIAL TRIFLUORMETHYL-SUBSTITUIERTER ZINN-HETEROCYCLEN

4,4-Bis(trifluoromethyl) substituted heterodienes of type (F3C)2C=N-C(R1)=X (X = O, S, NR2) react with tin(II) compounds to give cycloadducts.The cycloaddition process causes an 'Umpolung' at the carbon

Reaction Behaviour of Trifluoromethyl Groups. Synthesis of 1,3-Azoles from Trifluoromethyl-substituted Hetero-1,3-dienes

4,4-Bis(trifluoromethyl)-substituted 1-oxa-3-aza-1,3-butadienes 1, 1-thia-3-aza-1,3-butadienes 2 as well as 1,3-diaza-1,3-butadienes 3 on heating with tin(II) chloride yield 5-fluoro-4-trifluoromethyl-substituted oxazoles 4, thiazoles 5, and imidazoles 6,

SELEKTIVE EINFUEHRUNG VON FLUOR UND TRIFLUORMETHYLGRUPPEN IN HETEROCYCLISCHE SYSTEME SYNTHESE VON 5-FLUOR-4-TRIFLUORMETHYL-OXAZOLEN

N--imidoylchlorides 4 on heating with trimethyl phosphate yield 5,5-difluoro-4-difluoromethylen-2-oxazolines 5.In the presence of caesium fluoride the latter rearrange to give 5-fluoro-4-trifluoromethyl-oxazoles