78812-86-9Relevant academic research and scientific papers
REACTION OF HYDROXYMETHYL ARYL KETONES WITH AROMATIC HYDROCARBONS
Bal'on, Ya. G.,Smirnov, V. A.
, p. 1712 - 1715 (2007/10/02)
The readily obtainable products from the condensation of arylglyoxals with carboxamides react with benzene and its analogs in the presence of concentrated sulfuric acid or phosphorus pentoxide in trifluoroacetic acid with the formation of arylmethyl aryl ketones, which are used for the synthesis of substituted azoles.
ACTIVATED CARBOXYLATES FROM THE PHOTOOXYGENATION OF OXAZOLES. APPLICATION TO THE SYNTHESIS OF RECIFEIOLIDE AND OTHER MACROCYCLIC LACTONES.
Wasserman, Harry H.,Gambale, Ronald J.,Pulwer, Mitchell J.
, p. 1737 - 1740 (2007/10/02)
The oxazole system may serve as a protecting group for the carboxyl function.The carboxylate is generated under mild conditions of photooxygenation in high yield in the form of the reactive triamide.This reaction has been applied to the synthesis of macrocyclic lactones.
