78832-53-8

Basic information

• Product Name: 1-AMINONAPHTHALENE-D7
• Synonyms: 1-AMINONAPHTHALENE-D7;1-NaphthylaMine-d7;2,3,4,5,6,7,8-heptadeuterionaphthalen-1-amine
• CAS NO: 78832-53-8
• Molecular Formula: C₁₀H₉N
• Molecular Weight: 150.23
• EINECS: 205-138-7
• Product Categories: 13C & 2H Sugars;A;Alphabetical Listings;Stable Isotopes;Amines, Aromatics, Intermediates, Isotope Labeled Compounds, Miscellaneous Reagents
• Mol File: 78832-53-8.mol
• Article Data: 7

Chemical Properties

• Melting Point: 48-50 °C(lit.)
• Boiling Point: 301 °C(lit.)
• Appearance: /
• CAS DataBase Reference: 1-AMINONAPHTHALENE-D7(CAS DataBase Reference)
• NIST Chemistry Reference: 1-AMINONAPHTHALENE-D7(78832-53-8)
• EPA Substance Registry System: 1-AMINONAPHTHALENE-D7(78832-53-8)

Safety Data

• Hazard Codes: Xn,N
• Statements: 22-51/53
• Safety Statements: 24-61
• RIDADR: UN 2077 6.1/PG 3
• WGK Germany: 2
• Hazardous Substances Data: 78832-53-8(Hazardous Substances Data)

Usage

Uses

1-AMINONAPHTHALENE-D7 is a reagent used to synthesize various dyes used in the textile industry. This is the labeled analog.

Upstream product

• 80789-77-1 [D]₇-1-nitronaphthalene 
• 1146-65-2 naphthalene-d8 
• 134-32-7 1-amino-naphthalene 

Relevant articles and documents

Free-Amine-Directed Iridium-Catalyzed C?H Bond Activation and Cyclization of Naphthalen-1-amines with Diazo Compounds Leading to Naphtho[1,8-bc]pyridines

Iridium-catalyzed C?H activation and cyclization of naphthalen-1-amines with diazo compounds leading to naphtho[1,8-bc]pyridines have been developed. Different from the previous free-amine-directed C?H functionalization with diazo compounds that relied on the coordination of lone pair electrons or in situ formation of imine, this transformation passes through a five-membered iridacycle intermediate containing an N?Ir σ-bond. It offers an alternative approach for the synthesis of useful diverse naphtho[1,8-bc]pyridine derivatives in mild conditions. (Figure presented.).

Electrochemical ruthenium-catalyzed alkyne annulations by C-H/Het-H activation of aryl carbamates or phenols in protic media

Electrooxidative peri-C-H activation was accomplished by versatile ruthenium(ii) catalysis in terms of C-H/N-H and C-H/O-H functionalization. Thus, alkyne annulations proved viable with ample scope by organometallic C-H activation. The sustainable electrocatalysis exploited electricity, thereby avoiding the use of toxic transition metals as sacrificial oxidants. The robust ruthenium(ii)-electrocatalysis was operative in a protic alcohol/H2O reaction medium with excellent levels of position-, regio- and chemo-selectivity.

Mild conditions for deuteration of primary and secondary arylamines for the synthesis of deuterated optoelectronic organic molecules

Deuterated arylamines demonstrate great potential for use in optoelectronic devices, but their widespread utility requires a method for large-scale synthesis. The incorporation of these deuterated materials into optoelectronic devices also provides the op