80789-77-1

Basic information

• Product Name: 1-NITRONAPHTHALENE-D7
• Synonyms: 1-NITRONAPHTHALENE-D7;8-nitro-(1,2,3,4,5,6,7-2H7)naphthalene;Einecs 279-557-9
• CAS NO: 80789-77-1
• Molecular Formula: C10D7NO2
• Molecular Weight: 180.21
• EINECS: 279-557-9
• Mol File: 80789-77-1.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-NITRONAPHTHALENE-D7(CAS DataBase Reference)
• NIST Chemistry Reference: 1-NITRONAPHTHALENE-D7(80789-77-1)
• EPA Substance Registry System: 1-NITRONAPHTHALENE-D7(80789-77-1)

Safety Data

• Hazardous Substances Data: 80789-77-1(Hazardous Substances Data)

Usage

General Description

1-NITRONAPHTHALENE-D7 is a deuterated derivative of 1-nitronaphthalene, a chemical compound commonly used as a precursor in the production of various organic compounds. The deuterium substitution in the compound is a form of isotopic labeling and is utilized for various research and analytical purposes, including in studies related to environmental fate and transport, as well as in investigations of chemical reactions and processes involving 1-nitronaphthalene. The deuterated form, 1-NITRONAPHTHALENE-D7, is often used in applications such as mass spectrometry and nuclear magnetic resonance (NMR) spectroscopy, where the presence of deuterium can provide valuable information about the structure and behavior of the compound. Additionally, 1-NITRONAPHTHALENE-D7 may also be employed as a stable isotope internal standard in analytical chemistry methods, enabling accurate quantification and detection of 1-nitronaphthalene and related compounds.

Upstream product

• 1146-65-2 naphthalene-d8 

Downstream Products

• 78832-53-8 [D]₇-1-naphthylamine 

Relevant articles and documents

Free-Amine-Directed Iridium-Catalyzed C?H Bond Activation and Cyclization of Naphthalen-1-amines with Diazo Compounds Leading to Naphtho[1,8-bc]pyridines

Iridium-catalyzed C?H activation and cyclization of naphthalen-1-amines with diazo compounds leading to naphtho[1,8-bc]pyridines have been developed. Different from the previous free-amine-directed C?H functionalization with diazo compounds that relied on the coordination of lone pair electrons or in situ formation of imine, this transformation passes through a five-membered iridacycle intermediate containing an N?Ir σ-bond. It offers an alternative approach for the synthesis of useful diverse naphtho[1,8-bc]pyridine derivatives in mild conditions. (Figure presented.).

Electrochemical ruthenium-catalyzed alkyne annulations by C-H/Het-H activation of aryl carbamates or phenols in protic media

Electrooxidative peri-C-H activation was accomplished by versatile ruthenium(ii) catalysis in terms of C-H/N-H and C-H/O-H functionalization. Thus, alkyne annulations proved viable with ample scope by organometallic C-H activation. The sustainable electrocatalysis exploited electricity, thereby avoiding the use of toxic transition metals as sacrificial oxidants. The robust ruthenium(ii)-electrocatalysis was operative in a protic alcohol/H2O reaction medium with excellent levels of position-, regio- and chemo-selectivity.

Copper-mediated dehydrogenative biaryl coupling of naphthylamines and 1,3-azoles

A copper-mediated dehydrogenative biaryl cross-coupling of naphthylamines and 1,3-azoles has been developed. The key to its success is the introduction of N,N-bidentate coordination system based on the picolinamide directing group. The reaction proceeds s