78837-63-5

Basic information

• Product Name: Benzamide, N-[(1R,2R)-2-(phenylseleno)cyclohexyl]-, rel-
• CAS NO: 78837-63-5
• Molecular Formula: C19H21NOSe
• Molecular Weight: 358.342
• Mol File: 78837-63-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzamide, N-[(1R,2R)-2-(phenylseleno)cyclohexyl]-, rel-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, N-[(1R,2R)-2-(phenylseleno)cyclohexyl]-, rel-(78837-63-5)
• EPA Substance Registry System: Benzamide, N-[(1R,2R)-2-(phenylseleno)cyclohexyl]-, rel-(78837-63-5)

Safety Data

• Hazardous Substances Data: 78837-63-5(Hazardous Substances Data)

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 100-47-0 benzonitrile 
• 110-83-8 cyclohexene 

Downstream Products

• 4714-50-5 7-benzoyl-7-aza-bicyclo[4.1.0]heptane 

Relevant articles and documents

Amidoselenation of Olefins and Its Utilization for Synthesis of Allylic Amides

The reaction of phenylselenyl chloride with olefins in acetonitrile containing trifluoromethanesulfonic acid and water affords β-acetamidoalkyl phenyl selenides in good to excellent yields.This represents the first example of one-pot amidoselenation of mono- and disubstituted olefins.The reaction can be carried out in benzonitrile, propionitrile, butyronitrile, or ethyl cyanoacetate.It was confirmed that the amidoselenation reaction proceeds with trans stereospecifity.Oxidative elimination of the produced β-amidoalkyl phenyl selenides gives allylic amides selectively in good to excellent yields.These two reactions constitute a good method for conversion of olefins to allylic amides.