78870-57-2Relevant academic research and scientific papers
Stereoisomerization of α-hydroxy-β-sulfenyl-α,β- dimethyl naphthoquinones controlled by nonbonded sulfur-oxygen interactions
Latorre, Antonio,Rodríguez, Santiago,Jain, Amit,González, Florenci V.,Mata, José A.
, p. 2098 - 2101 (2013/03/13)
The anti α-hydroxy-β-sulfenyl-α,β-dimethyl naphthoquinones isomerize in basic media into syn/anti mixtures of isomers, giving the syn isomer as the major product. Conversely, anti α-hydroxy-β-alkoxy-α,β-dimethyl naphthoquinones isomerize to furnish the an
