78880-71-4

Basic information

• Product Name: Benzoic acid, 2-(chlorothio)-, methyl ester
• CAS NO: 78880-71-4
• Molecular Formula: C8H7ClO2S
• Molecular Weight: 202.661
• Mol File: 78880-71-4.mol

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2-(chlorothio)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-(chlorothio)-, methyl ester(78880-71-4)
• EPA Substance Registry System: Benzoic acid, 2-(chlorothio)-, methyl ester(78880-71-4)

Safety Data

• Hazardous Substances Data: 78880-71-4(Hazardous Substances Data)

Upstream product

• 119-80-2 2,2'-dithiobenzoic acid 
• 4892-02-8 Methyl thiosalicylate 

Downstream Products

• 109257-97-8 2-benzothiazol-2-yldisulfanyl-benzoic acid methyl ester 
• 182687-94-1 2-(Cyclopenta-1,3-dienylsulfanyl)-benzoic acid methyl ester 
• 1393829-09-8 C₁₀H₉N₃O₂S₂ 
• 1393829-31-6 C₁₆H₁₃N₃O₂S₂ 
• 1393829-45-2 C₁₅H₁₂N₄O₂S₂ 
• 1402735-01-6 methyl 2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)disulfanyl)benzoate 
• 1402734-88-6 methyl 2-((5-methyl-1,3,4-thiadiazol-2-yl)disulfanyl)benzoate 
• 1402734-97-7 methyl 2-((5-(pyridin-3-yl)-1,3,4-oxadiazol-2-yl)disulfanyl) benzoate 
• 1402734-94-4 methyl 2-((5-phenyl-1,3,4-oxadiazol-2-yl)disulfanyl)benzoate 
• 1402734-84-2 2-[5-(2-hydroxy-phenyl)-[1,3,4]thiadiazol-2-yldisulfanyl]benzoic acid methyl ester 
• 1402734-64-8 methyl 2-((1,3,4-thiadiazol-2-yl)disulfanyl)benzoate 
• 1421695-48-8 C₁₆H₁₁NO₄S 
• 917472-02-7 2-(2-methyl-benzo[b]thiophen-3-ylsulfanyl)-benzoic acid methyl ester 
• 3844-31-3 trans-thioindigo 

Relevant articles and documents

Synthesis and biological evaluation of nonsymmetrical aromatic disulfides as novel inhibitors of acetohydroxyacid synthase

46 Novel nonsymmetrical aromatic disulfides containing [1,3,4]thiadiazole or [1,3,4]oxadiazole groups were synthesized and their biological activities were evaluated as inhibitors of acetohydroxyacid synthase (AHAS, EC 2.2.1.6). Besides their strong in vitro inhibition against plant AHAS, compounds 3e and 3f also display 80-100% post-emergence herbicidal activities in greenhouse bioassay at 1500 g/ha dosage. The assay of exogenous branched-chain amino acids supplementation on rape root growth of 3e suggests that the herbicidal activity has relationship with AHAS inhibition.

NOVEL ANDROGENS

The compounds of the subject invention have a structure according to formula I: wherein X is S or SO2; R1 is (1C-6C)alkyl, (3C-6C)alkenyl, or (3C-6C)alkynyl, each optionally subst ituted with (3C-6C)cycloalkyl, OH, OC(O)(1C-4C)alkyl, (1C- 4C)alkoxy, halogen, cyano, formyl, C(O)(1C-4C)alkyl, CO2H, CO2(1C- 4C)alkyl, C(O)NR5R6, S(O)(1C-4C)alkyl or S(O)2(1C-4C)alkyl; R2 is hydrogen, (1C-4C)alkyl or C(O)(1C-4C)alkyl; R3 is a phenyl group optionally substituted with (1C-4C)alkyl, (1C-4C)fluoroalkyl, (1C-4C)alkoxy, (1C-4C)fluoroalkoxy, halogen, cyano or nitro; or R3 is a 5- or 6-membered aromatic heterocyclic ring structure optionally substituted with (1C-4C)alkyl, (1C-4C)fluoroalkyl, (1C-4C)alkoxy, halogen or cyano; R4 is a phenyl group or an aromatic 6-membered heterocycle, substituted at the ortho position with 1-hydroxy(1C-4C)alkyl, (1C-4C)alkoxy, C(O)(1C- 4C)alkyl, CO2(1C-4C)alkyl, C(O)NH2, cyano, nitro, or CH=NOR7, and optionally further substituted with (1C-2C)alkyl, (1C-2C)fluoroalkyl or halogen; R5 is 2-pyridyl optionally substituted with (1C-2C)alkyl, (1C- 2C)fluoroalkyl or halogen; or R5 and R6 are independently hydrogen or (1C-4C)alkyl; R7 is hydrogen or C(O)(1C-4C)alkyl; R8 , R9 , R10 are independently hydrogen, (1C-2C)alkyl, fluoro or chloro; or a salt or hydrate form thereof.

Thiopyranothiopyran Chemistry. 5. Synthesis of Dibenzothiopyranothiopyran-6,12-dione (Thioepindolidione)

Tne novel thioepindolidione, a derivative of a thiopyranothiopyran, was synthesized from thiochroman-4-one.The absorption and fluorescence characteristics of thioepindolidione are compared with those of thioindigo and epindolidione.