789-54-8

Upstream product

• 128-37-0 2,6-di-tert-butyl-4-methyl-phenol 

Downstream Products

• 56108-38-4 Phosphorous acid 2,6-di-tert-butyl-4-methyl-phenyl ester diphenyl ester 
• 128851-18-3 Phosphorous acid 2,6-di-tert-butyl-4-methyl-phenyl ester bis-(2,2,6,6-tetramethyl-piperidin-4-yl) ester 
• 125750-30-3 (2,6-t-Bu₂-4-MeC₆H₂O)phenylethinyl-chlorophosphine 
• 93701-63-4 6-(2,6-Di-tert-butyl-4-methyl-phenoxy)-5,7-dioxa-6-phospha-dibenzo[a,c]cycloheptene 
• 78902-17-7 Phosphorous acid 2,6-di-tert-butyl-4-methyl-phenyl ester dioctyl ester 
• 128851-19-4 C₃₁H₅₇OPS₂ 
• 1100-34-1 2-(2,6-Di-tert-butyl-4-methylphenoxyl)-1,3,2-benzo-dioxaphosphol 
• 75895-57-7 2,6-di-tert-butyl-p-tolyl tetraethylphosphorodiamidite 
• 128851-24-1 Phosphorous acid diallyl ester 2,6-di-tert-butyl-4-methyl-phenyl ester 
• 103869-70-1 Phosphorous acid 2,6-di-tert-butyl-4-methyl-phenyl ester diisopropyl ester 
• 96357-74-3 2,4,6-tris(2,6-di-tert-butyl-4-methylphenoxy)-1,3,5,2,4,6,trioxatriphosphorinane 
• 78902-28-0 C₁₅H₂₅O₃P 
• 171737-25-0 C₃₀H₄₈O₅P₂ 

Relevant academic research and scientific papers

Monooxychlorophosphine as a novel and efficient ligand for palladium-catalyzed Suzuki-Miyaura cross-coupling of aryl chlorides

A new sterically hindered monooxychlorophosphine was synthesized and the complex generated in situ from its reaction with Pd2(dba)3 promoted the Suzuki-Miyaura reactions of arylboronic acids with aryl chlorides in good yields. Georg Thieme Verlag Stuttgart.

A copper- and amine-free Sonogashira reaction employing chlorophosphine as new and efficient ligand

An efficient palladium-catalyzed copper- and amine-free Sonogashira coupling reaction of aryl bromides and chlorides was studied using a sterically hindered monooxychlorophosphine as new ligand. The use of 2 mol% Pd(OAc) 2 in the presence of K2CO3 allows the coupling reaction to proceed at mild condition with good to excellent yields.

NMR and X-ray crystallographic studies of unsymmetrical 25,26;27,28-dibridged para-tert-butyl calix[4]arene bisphosphites with a large "through-space" P-P coupling

Three 25,26-bridged para-tert-butyl-calix[4]arene phosphites, 1-3, have been synthesized by linking two proximal phenolic oxygen atoms of para-tert-butyl-calix[4]arene to a P(OR) [R = 2,6-But 2-4-Me-C6H2 (1), 2,

Reactions of ( THF) W( CO) 5 with some diphosphenes carrying bulky aryl and phenoxy groups

The reaction of (THF)W(CO)5 (THF = tetrahydrofuran) with asymmetrical diphosphenes carrying bulky aryl and phenoxy groups gave end-on-type complexes on either phosphorus atom. One of the complexes was analyzed by X-ray crystallography indicatin

Synthese und Reaktivitaet von Phenylethinyl-substituierten Phosphenium-Ion-Komplexen (R)(R')P=MoCp'(CO)2; Darstellung von Clusterverbindungen, die einen 1-Cobalta-2-Phospha-Heteroallyl Synthesebaustein enthalten

The synthesis of the phenylethinyl-chlorophosphines (R)(Cl)P(CC-Ph) (R = 2,6-tBu2-4-MeC6H2O: IVa; R = 2,4,6-tBu3C6H2O: IVb) is described.IV reacts with Cp'(CO)3Mo-, VII, (Cp' = η5-C5H5, ν5-C5Me5) t