78945-05-8

Basic information

• Product Name: S-phenyl pent-4-enethioate
• Synonyms: S-phenyl pent-4-enethioate
• CAS NO: 78945-05-8
• Molecular Weight: 192.282
• Mol File: 78945-05-8.mol

Chemical Properties

• CAS DataBase Reference: S-phenyl pent-4-enethioate(CAS DataBase Reference)
• NIST Chemistry Reference: S-phenyl pent-4-enethioate(78945-05-8)
• EPA Substance Registry System: S-phenyl pent-4-enethioate(78945-05-8)

Safety Data

• Hazardous Substances Data: 78945-05-8(Hazardous Substances Data)

Upstream product

• 591-80-0 pent-4-enoic acid 
• 882-33-7 diphenyldisulfane 
• 201230-82-2 carbon monoxide 
• 5162-44-7 1-bromo-4-butene 
• 108-98-5 thiophenol 
• 2564-83-2 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical 
• 33574-02-6 cyclopropylmethyl iodide 
• 28074-23-9 phenylsulfenyl bromide 
• 14933-91-6 N-phenyl-benzenesulphenamide 
• 884-09-3 phenyl thiobenzoate 

Downstream Products

• 28215-02-3 (2-nitro-phenyl)-phenyl disulfide 
• 58170-51-7 1-(4-morpholinyl)-4-penten-1-one 

Relevant articles and documents

Manganese(iii)-promoted thiocarbonylation of alkylborates with disulfides: synthesis of aliphatic thioesters

A Mn(iii)-promoted thiocarbonylation procedure toward the synthesis of thioesters has been developed. By employing easily available disulfides and potassium alkyltrifluoroborates as the starting materials, and cheap and non-toxic Mn(OAc)3·2H2O as the promotor, a broad range of thioesters were synthesized in good to excellent yieldsviaradical intermediates.

Rhodium-catalyzed carbonylative coupling of alkyl halides with thiols: a radical process faster than easier nucleophilic substitution

How to make a carbonylative coupling faster than the easier nucleophilic substitution? In this communication, a rhodium-catalyzed radical-based carbonylative coupling of alkyl halides with thiolphenols has been realized. Thioesters were isolated in good y