78960-85-7Relevant articles and documents
Perfluoroalkyl and -aryl Zinc Ate Complexes: Generation, Reactivity, and Synthetic Application
Wang, Xuan,Hirano, Keiichi,Kurauchi, Daisuke,Kato, Hisano,Toriumi, Naoyuki,Takita, Ryo,Uchiyama, Masanobu
, p. 10993 - 10996 (2015/11/10)
A combination of dimethylzinc, perfluoroalkyl iodide, and LiCl afforded a new type of perfluoroalkyl (RF) zinc ate complex. These complexes show much greater thermal stability than conventional perfluorinated metal species, such as RF-lithium species and Grignard reagents, and they can be used at room temperature or higher. The results of DFT calculations on the origin of the enhanced stability are reported and the synthetic utility of RF-zincate complexes is demonstrated. The magnificent ate: A combination of dimethylzinc, perfluoroalkyl iodide, and LiCl afforded a new type of perfluoroalkyl (RF) zinc ate complex. These complexes show greater thermal stability than conventional perfluorinated metal species and they can be used at room temperature or higher. The results of DFT calculations on the origin of the enhanced stability are reported and the synthetic utility of RF-zincate complexes is demonstrated.
A Remarkably Simple Perfluoroalkylation in the Presence of an Electron Mediator
Kitazume, Tomoya,Ikeya, Takanobu
, p. 2349 - 2350 (2007/10/02)
-
PALLADIUM AND NICKEL-CATALYZED PERFLUOROALKYLATION OF ALDEHYDES USING ZINC AND PERFLUOROALKYL HALIDES
O'Reilly, Neil J.,Maruta, Masamichi,Ishikawa, Nobuo
, p. 517 - 520 (2007/10/02)
A room temperature method for the conversion of perfluoroalkyl iodides to α-perfluoroalkyl carbinols under Pd or Ni catalysis is reported.The use of trifluoromethyl bromide provides an economical procedure for trifluoromethyl substituted carbinols.
