78968-94-2

Upstream product

• 79027-28-4 (2S)-3-(benzyloxy)-2-methylpropanal 
• 77396-92-0 ((R)-4-Benzyloxy-3-methyl-but-1-ynyl)-trimethyl-silane 

Downstream Products

• 77396-90-8 (Z)-(R)-5-Benzyloxy-4-methyl-2-trimethylsilanyl-pent-2-en-1-ol 
• 77396-91-9 [(S)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-2-trimethylsilanyl-oxiranyl]-methanol 
• 81520-04-9 (2S,3S,4S)-5-(benzyloxy)-2,3-epoxy-4-methyl-1-pentanol 

Relevant academic research and scientific papers

Stereoselective synthesis of functionalized trisubstituted olefins via palladium(0)-catalyzed cross-coupling reaction.

[reaction: see text]. A highly flexible and stereoselective protocol for the synthesis of branched (E)- and (Z)-trisubstituted alkenes has been developed. The key steps are hydrozirconation-iodination of (1-alkynyl)trimethylsilane followed by Negishi-type

Further studies on stereospecific epoxidation of allylic alcohols Iltifat Hasan

A stereosepcific synthesis of the epoxides 4 and 12c is described.